-10-200 °C temperature (isothermal) -10-220 °C temperature (programmed)
Beta-Wert
500
df
0.12 μm
Methode(n)
gas chromatography (GC): suitable
L × ID
30 m × 0.25 mm
Aktive Matrixgruppe
non-bonded; 2,6-di-O-pentyl-3-methoxy derivative of β-cyclodextrin phase
Anwendung(en)
agriculture chemicals and industrial polymers cleaning products clinical cosmetics environmental flavors and fragrances food and beverages forensics and toxicology life science and biopharma personal care pharmaceutical (small molecule)
CHIRALDEX B-DA requires that analytes possess a minimum of two ring structures, one of which is unsaturated (aromatic) α, β to the stereogenic center. Examples include fluoxetine, methylphenidate and chloropheniramine. Inclusion complexation or proper fit between the analyte and cyclodextrin cavity is the dominant enantioselectivity mechanism for the DA series. There must be an includable group α or β to the stereogenic center for chiral recognition. Since CHIRALDEX DA columns most effectively separate multi-ring analytes, analysis temperatures are often higher than 150°C. Enantioselectivity has been observed at temperatures >200°C (fluoxetine acetyl derivative).
Chemische/physikalische Beständigkeit
Temp. Limits:
-10 °C to 200 °C isothermal, 220 °C programmed
Sonstige Hinweise
We offer a variety of chromatography accessories including analytical syringes
Rechtliche Hinweise
Astec is a registered trademark of Merck KGaA, Darmstadt, Germany
Structurally informative response patterns of some monoterpenoids found in volatile oils to gas chromatography on two commercial dipentylated cyclodextrin phases
Betts, T.J.
Journal of Chromatography A, 639 (2), 366-370 (1993)
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