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Merck

31173

Sigma-Aldrich

Ammoniumcer(IV)-sulfat Dihydrat

≥99%

Synonym(e):

Cer(IV)-ammoniumsulfat

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About This Item

Lineare Formel:
Ce(NH4)4(SO4)4 · 2H2O
CAS-Nummer:
Molekulargewicht:
632.55
MDL-Nummer:
UNSPSC-Code:
12352300
PubChem Substanz-ID:

Assay

≥99%

Eignung der Reaktion

reagent type: catalyst
core: cerium

Verunreinigungen

≤0.005% heavy metals (as Pb)
≤0.005% insoluble in acid

mp (Schmelzpunkt)

130 °C (lit.)

Anionenspuren

chloride (Cl-): ≤10 mg/kg
phosphate (PO43-): ≤50 mg/kg

Kationenspuren

Fe: ≤50 mg/kg

SMILES String

N.N.N.N.O.O.[Ce+4].OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O

InChI

1S/Ce.4H3N.4H2O4S.2H2O/c;;;;;4*1-5(2,3)4;;/h;4*1H3;4*(H2,1,2,3,4);2*1H2/q+4;;;;;;;;;;/p-4

InChIKey

VCNAMBGKEDPVGQ-UHFFFAOYSA-J

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Allgemeine Beschreibung

Ammonium cerium(IV) sulfate dihydrate (tetraammonium cerium(IV) sulphate dihydrate) is commonly employed as starting material for various organic syntheses. It is widely employed as oxidizing agent. Its thermal decomposition and thermal characteristics have been reported.[1]

Anwendung

Ammonium cerium(IV) sulfate may be used for the determination of urinary iodine by ammonium persulfate digestion on microplate (APDM) method[2] and colorimetric method.[3]
Ammonium cerium(IV) sulfate was used in thin-layer chromatography for the detection of anti-depreβant drugs in human blood and urine samples. [4]

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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N Sadeg et al.
Clinical chemistry, 43(3), 498-504 (1997-03-01)
We evaluated the clinical utility of an automated HPLC system (Remedi, Bio-Rad) for identification of drugs and metabolites in biological fluids. Serum or urine or both from 354 consecutive cases of poisoning were analyzed by the system and by a
T Ohashi et al.
Clinical chemistry, 46(4), 529-536 (2000-04-12)
Urinary iodine is a good biochemical marker for control of iodine deficiency disorders. Our aim was to develop and validate a simple, rapid, and quantitative method based on the Sandell-Kolthoff reaction, incorporating both the reaction and the digestion process into
Thermal behaviour of sulphato and nitrato complexes of cerium (IV).
Pokol G, et al.
J. Therm. Anal., 42(2-3), 343-359 (1994)
Fast colorimetric method for measuring urinary iodine.
Daniella Gnat et al.
Clinical chemistry, 49(1), 186-188 (2003-01-01)
K Tsuda et al.
Clinical chemistry, 41(4), 581-585 (1995-04-01)
We have modified an automated measurement system of urinary iodine (UI) and established a sensitive UI assay system by using ultraviolet (UV) digestion. The automated system is sensitive enough to detect concentrations of UI < 0.78 mumol/L (< 10 micrograms/dL)

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