07033

N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amin

≥99.0%

• Synonym(e): (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)-bis-(1-phenylethyl)-amin, BIPOL-A1(S), O,O′-(2,2′-Biphenyldiyl)-N,N-bis-[(S)-1-phenylethyl]-phosphoramidit
• Empirische Formel (Hill-System): C₂₈H₂₆NO₂P
• CAS-Nummer: 376355-58-7
• Molekulargewicht: 439.49
• MDL-Nummer: MFCD08277033
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329748328
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: ≥99.0%
• Form: powder
• Optische Aktivität: [α]/D -250±10°, c = 1 in toluene
• Eignung der Reaktion: reaction type: click chemistry
• mp (Schmelzpunkt): 99-102 °C
• SMILES String: C[C@H](N([C@@H](C)c1ccccc1)P2Oc3ccccc3-c4ccccc4O2)c5ccccc5
• InChI: 1S/C28H26NO2P/c1-21(23-13-5-3-6-14-23)29(22(2)24-15-7-4-8-16-24)32-30-27-19-11-9-17-25(27)26-18-10-12-20-28(26)31-32/h3-22H,1-2H3
• InChIKey: JISGHECLGYELKD-UHFFFAOYSA-N

Beschreibung

Anwendung

N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:

• In the iridium catalyzed allylic arylation.
• To prepare a copper complex (Cu₂X₂L₃), which is used to detect the transmetalation intermediates in asymmetric addition reactions using ZnEt₂.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)