901169

trans-Bis(methyldiphenylphosphine)(2-methylphenyl)nickel(II) chloride

• Synonym(e): trans-(PPh₂Me)₂Ni(o-tolyl)Cl
• Empirische Formel (Hill-System): C₃₃H₃₃ClNiP₂
• CAS-Nummer: 1594112-89-6
• Molekulargewicht: 585.71
• UNSPSC-Code: 12352200

Eigenschaften

• Form: powder or solid
• Eignung der Reaktion: core: nickel; reaction type: Cross Couplings; reagent type: catalyst
• mp (Schmelzpunkt): 152-157 °C
• SMILES String: Cl[Ni](PC([H])([H])[H])(P(C1=C([H])C([H])=C([H])C([H])=C1[H])(C2=C([H])C([H])=C([H])C([H])=C2[H])C([H])([H])[H])C3=C(C([H])([H])[H])C([H])=C([H])C([H])=C3[H].[H]C4=C(C5=C([H])C([H])=C([H])C([H])=C5[H])C([H])=C([H])C([H])=C4[H]

Beschreibung

Anwendung

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)₂, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

Sonstige Hinweise

• Technology Spotlight: Jamison Nickel (II) Precatalysts
• A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

Rechtliche Hinweise

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

Sicherheitshinweise

• Lagerklassenschlüssel: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable