693979

(1E,2E)-1,2-Bis-(2,6-Diisopropylphenylimino)-ethan

90%

• Synonym(e): Glyoxal-bis-(2,6-diisopropylanil), N,N′-Bis-(2,6-diisopropylphenyl)-1,4-diazabutadien, N,N′-Bis-(2,6-diisopropylphenyl)-ethandiimin
• Lineare Formel: (C₃H₇)₂C₆H₃NCHCHNC₆H₃(C₃H₇)₂
• CAS-Nummer: 74663-75-5
• Molekulargewicht: 376.58
• MDL-Nummer: MFCD03838856
• UNSPSC-Code: 12352300
• PubChem Substanz-ID: 329761636
• NACRES: NA.22

Eigenschaften

• Assay: 90%
• Form: solid
• Eignung der Reaktion: reagent type: ligand
• mp (Schmelzpunkt): 105-109 °C
• SMILES String: CC(C)c1cccc(C(C)C)c1\N=C\C=N\c2c(cccc2C(C)C)C(C)C
• InChI: 1S/C26H36N2/c1-17(2)21-11-9-12-22(18(3)4)25(21)27-15-16-28-26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3/b27-15+,28-16+
• InChIKey: JWVIIGXMTONOFR-DPCVLPDWSA-N

Beschreibung

Anwendung

• Reactant in preparation of derived ruthenium olefin metathesis catalysts
• N-cyclic carbene ligand

Catalyst in:

• Palladium-catalyzed aerobic alc. oxidn. supported by a-diimine ligands
• Regioselective alkylation in presence of ruthenium-bisimine catalytic precursors
• N-arylation of aromatic amines
• Preparation of ruthenium nitrosyl alpha-diimine and iminoketone complexes as catalysts for transfer hydrogenation of ketones and atom transfer radical polymerization reactions

Sicherheitshinweise

• Lagerklassenschlüssel: 13 - Non Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable