659622

(S)-BINAPINE-Rhodium-Komplex

• Synonym(e): [(S)-BINAPINE-(cyclooctadien)-rhodium(I)]-tetrafluoroborat
• Empirische Formel (Hill-System): C₆₀H₆₀BF₄P₂Rh
• CAS-Nummer: 1046806-02-3
• Molekulargewicht: 1032.78
• MDL-Nummer: MFCD07782007
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24884435

Eigenschaften

• mp (Schmelzpunkt): >300 °C
• SMILES String: [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CC(C)(C)P2Cc3ccc4ccccc4c3-c5c(ccc6ccccc56)[C@@H]2[C@@H]7P(Cc8ccc9ccccc9c8-c%10c7ccc%11ccccc%10%11)C(C)(C)C
• InChI: 1S/C52H48P2.C8H12.BF4.Rh/c1-51(2,3)53-31-37-25-23-33-15-7-11-19-39(33)45(37)47-41-21-13-9-17-35(41)27-29-43(47)49(53)50-44-30-28-36-18-10-14-22-42(36)48(44)46-38(32-54(50)52(4,5)6)26-24-34-16-8-12-20-40(34)46;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h7-30,49-50H,31-32H2,1-6H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t49-,50-,53+,54+;;;/m1.../s1
• InChIKey: ONKIOXVXGSKHFA-NBAVNVHNSA-N

Beschreibung

Anwendung

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Demonstates excellent enantioselectivity and reactivity for the asymmetric hydrogenation of Z-β-aryl(β-acylamino)acrylates.

Sicherheitshinweise

• Lagerklassenschlüssel: 13 - Non Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)