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239321

Sigma-Aldrich

Sulfite de sodium

ACS reagent, ≥98.0%

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About This Item

Formule linéaire :
Na2SO3
Numéro CAS:
Poids moléculaire :
126.04
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.21

Qualité

ACS reagent

Niveau de qualité

Agence

suitable for SM 5210

Pureté

≥98.0%

Forme

powder or crystals

Impuretés

Free acid, passes test
≤0.005% insolubles
≤0.03 meq/g Titr. free base

pH

9.0-10.5 (25 °C, 126 g/L)

Solubilité

water: soluble 126 g/L at 20 °C

Traces d'anions

chloride (Cl-): ≤0.02%

Traces de cations

Fe: ≤0.001%
heavy metals (as Pb): ≤0.001%

Chaîne SMILES 

[Na+].[Na+].[O-]S([O-])=O

InChI

1S/2Na.H2O3S/c;;1-4(2)3/h;;(H2,1,2,3)/q2*+1;/p-2

Clé InChI

GEHJYWRUCIMESM-UHFFFAOYSA-L

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Description générale

Sodium sulfite is a water-soluble inorganic salt that is commonly used as a reducing agent. It is also used for sulfonation and sulfomethylation reactions. Additionally, it is used in the textile industry as a bleaching, de-sulfurizing, and dechlorinating agent. As an oxygen and free chlorine scavenger, Na2SO3 is employed in the water treatment process. Sodium sulfite participates in the purification and isolation of aldehydes and ketones by forming adducts with them. Other uses include the production of sodium thiosulfate, detergents, and dyes.

Application

Sodium sulfite can be used:
  • As a reducing agent in the hydroxylation of arylboronic acids and arylboronic esters into corresponding phenols.
  • In the transformation of α-amino alcohol methanesulfonate hydrochlorides to sodium α-amino alkanesulfonates.
  • As a SO2 precursor in the multigram synthesis of DABCO·(SO2)2 abbreviated as DABSO.

Code de la classe de stockage

13 - Non Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Reaction kinetics of sodium sulfite oxidation by the rapid-mixing method.
Barron CH and O'Hern HA.
Chemical Engineering Science, 21(5), 397-404 (1966)
New plasticizers for wheat gluten films.
Irissin-Mangata J, et al.
European Polymer Journal, 37(8), 1533-1541 (2001)
Amber R Boles et al.
Biotechnology and bioengineering, 109(3), 637-646 (2011-10-22)
A novel sulfur-utilizing perchlorate reducing bacterial consortium successfully treated perchlorate (ClO₄⁻) in prior batch and bench-scale packed bed reactor (PBR) studies. This study examined the scale up of this process for treatment of water from a ClO ₄⁻ and RDX contaminated
Yisu Han et al.
ACS chemical biology, 14(4), 619-635 (2019-03-09)
APEX is an engineered peroxidase that catalyzes the oxidation of a wide range of substrates, facilitating its use in a variety of applications from subcellular staining for electron microscopy to proximity biotinylation for spatial proteomics and transcriptomics. To further advance
Fabian Leinisch et al.
Chemical research in toxicology, 24(12), 2217-2226 (2011-10-19)
Nitrone spin traps such as 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) are commonly used for free radical detection. Though proven examples are rare, artifact formation must be considered. For example, the Forrester-Hepburn mechanism yields the same radical adduct as that formed by genuine radical

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This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.

This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.

This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.

This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.

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