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935719

Sigma-Aldrich

Cobalt(II) nitrate hexahydrate

greener alternative

≥99.9% trace metals basis

Synonyme(s) :

Cobalt Nitrate Hexahydrate, Cobalt dinitrate hexahydrate, Cobaltous nitrate, Cobaltous nitrate hexahydrate, Nitric acid, cobalt(II) salt

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About This Item

Formule linéaire :
Co(NO3)2 · 6H2O
Numéro CAS:
Poids moléculaire :
291.03
Numéro MDL:
Code UNSPSC :
12352302
Nomenclature NACRES :
NA.21

Niveau de qualité

Pureté

≥99.9% trace metals basis

Forme

powder, crystals or granules (Chunks)

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Couleur

faint red to very dark red

Pf

55 °C (lit.)

Solubilité

soluble, clear to slightly hazy

Autre catégorie plus écologique

Chaîne SMILES 

O.O.O.O.O.O.[Co++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Co.2NO3.6H2O/c;2*2-1(3)4;;;;;;/h;;;6*1H2/q+2;2*-1;;;;;;

Clé InChI

QGUAJWGNOXCYJF-UHFFFAOYSA-N

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Description générale

Cobalt(II)nitrate hexahydrate is red solid which is soluble in water and polar solvents. It is also known as hexaaquacobalt(II) nitrate consists of [Co(OH2)6]2+ and [NO3]ions.
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Application

Cobalt(II) nitrate hexahydrate, has been widely used for the synthesis of Cobalt oxide nanoparticles and cobalt containing compounds. For Example:Cobalt(II) nitrate hexahydrate is used to synthesize cobalt-cobalt oxide/N-doped carbon hybrids, which are then used as hydrogen evolution reaction (HER) or superior oxygen evolution reaction (OER) catalysts in water splitting.

It has also been used as a primary precursor material in the synthesis of Co3O4 nanocrystals in various shapes such as nanosheets, nanocubes, and nanobelts as a catalyst for methane combustion.

Furthermore, the reaction of Cobalt(II) nitrate hexahydrate with Nickel(II) nitrate hexahydrate produces Nickel-cobalt layered double hydroxide nanosheets in presence of methanol and CTAB, which is used as a high-performance electrocatalyst for oxygen evolution.

In addition, Cobalt(II) nitrate hexahydrate precursor powder is calcined to produce Co3O4 nanotubes using the template synthesis method. The Co3O4 nano-tubes, nanorods, and nanoparticles that have been created are used in gas sensing systems and as anode materials for Li-ion batteries

Cobalt hydroxide and layered double hydroxides (CH@LDH) have been synthesized using Cobalt(II)nitrate hexahydrate as a sulfur host for lithium–sulfur batteries.

It is well studied that, Cobalt(II) nitrate hexahydrate is used as a heterogeneous catalyst Co/SiO2 with Silica support, for Fischer−Tropsch Synthesis.

Cobalt(II) Nitrate Hexahydrate is also used as a catalyst for the synthesis of 5-Carboxanilide-dihydropyrimidinone derivatives by the condensation reaction of acetoacetanilide, aldehyde and urea/thiourea.

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 2 Inhalation

Organes cibles

Lungs

Code de la classe de stockage

5.1B - Oxidizing hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Fundamentals of melt infiltration for the preparation of supported metal catalysts. The case of Co/SiO2 for Fischer-Tropsch synthesis
Eggenhuisen T M, et al.
Journal of the American Chemical Society, 132, 18318-18325 (2010)
Nickel?cobalt layered double hydroxide nanosheets as high-performance electrocatalyst for oxygen evolution reaction
Jiang J, et al.
Journal of Power Sources, 278, 445-451 (2015)
Co3O4 Nanomaterials in Lithium-Ion Batteries and Gas Sensors
Li W Y, et al.
Advanced Functional Materials , 15, 851-857 (2005)
Selective catalytic reduction of nitrogen oxides by ammonia over Co3O4 nanocrystals with different shapes
Meng B, et al.
Applied Catalysis. B, Environmental, 129, 491-500 (2013)
In situ cobalt-cobalt oxide/N-doped carbon hybrids as superior bifunctional electrocatalysts for hydrogen and oxygen evolution
Jin H, et al.
Journal of the American Chemical Society, 137, 2688-2694 (2015)

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