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745480

Sigma-Aldrich

Zinc isopropylsulfinate

95%

Synonyme(s) :

Baran Isopropylation Reagent, Baran IPS Reagent, Bis((isopropylsulfinyl)oxy)zinc, IPS

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About This Item

Formule empirique (notation de Hill) :
C6H14O4S2Zn
Numéro CAS:
1416821-55-0
Poids moléculaire :
279.69
Numéro MDL:
MFCD24386390
Code UNSPSC :
12352001
ID de substance PubChem :
329764984
Nomenclature NACRES :
NA.22

Essai

95%

Forme

solid

Capacité de réaction

reaction type: Allylation
reaction type: C-C Bond Formation

Pertinence de la réaction

reagent type: catalyst
reaction type: C-H Activation
reagent type: diversification reagent

Pf

161-166 °C

Groupe fonctionnel

sulfinic acid

Chaîne SMILES 

CC(C)S(=O)O[Zn]OS(=O)C(C)C

InChI

1S/2C3H8O2S.Zn/c2*1-3(2)6(4)5;/h2*3H,1-2H3,(H,4,5);/q;;+2/p-2

Clé InChI

PEEMMWYYSHSBTQ-UHFFFAOYSA-L

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Application

Zinc isopropylsulfinate (IPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Liaison

Frequently Asked Questions are available for this Product.

Notes préparatoires

may contain up to 1 mole eq ZnCl2

Autres remarques

Previously sold under product number L511161

Pictogrammes

CorrosionExclamation markEnvironment
GHS05,GHS07,GHS09

Mention d'avertissement

Danger

Mentions de danger

H314,H335,H410

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number
MKCN1076
MKCJ2637
MKCD0333
MKCB0914V
MKBX5822V

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Si vous avez besoin d'une version particulière, vous pouvez rechercher un certificat spécifique par le numéro de lot.

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Meiqi Niu et al.
eLife, 9 (2020-07-03)
The intraparietal sulcus (IPS) is structurally and functionally heterogeneous. We performed a quantitative cyto-/myelo- and receptor architectonical analysis to provide a multimodal map of the macaque IPS. We identified 17 cortical areas, including novel areas PEipe, PEipi (external and internal
Bonnie Bailet et al.
The Science of the total environment, 745, 140948-140948 (2020-08-01)
Ecological assessment of lakes and rivers using benthic diatom assemblages currently requires considerable taxonomic expertise to identify species using light microscopy. This traditional approach is also time-consuming. Diatom metabarcoding is a promising alternative and there is increasing interest in using
Jasmine Siew Min Chia et al.
Frontiers in pharmacology, 11, 92-92 (2020-03-21)
Zerumbone has shown great potential in various pathophysiological models of diseases, particularly in neuropathic pain conditions. Further understanding the mechanisms of action is important to develop zerumbone as a potential anti-nociceptive agent. Numerous receptors and pathways function to inhibit and
Xiaopeng Guo et al.
Environmental science and pollution research international, 23(24), 24758-24767 (2016-09-24)
This paper studies the relationship among carbon emissions, GDP, and logistics by using a panel data model and a combination of statistics and econometrics theory. The model is based on the historical data of 10 typical provinces and cities in
Thapanee Srichumpong et al.
Dental materials journal, 38(3), 378-387 (2019-03-15)
The mica-based glass-ceramics were prepared in the SiO2-Al2O3-MgO-MgF2-SrCO3-CaCO3-CaF2-P2O5 glass system. There were four mica-based glass-ceramics produced in this study according to the pigment added (CeO2 or Pr-ZrSiO4/Fe-ZrSiO4) and crystallization time (5-35 min). Four dental glass-ceramics, which were leucite-based, lithium disilicate-based
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