703915

RuCl(p-cymene)[(S,S)-Ts-DPEN]

• Synonyme(s) : [N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
• Formule empirique (notation de Hill): C₃₁H₃₅ClN₂O₂RuS
• Numéro CAS: 192139-90-5
• Poids moléculaire : 636.21
• Numéro MDL: MFCD14155881
• Code UNSPSC : 12352116
• ID de substance PubChem : 329762076
• Nomenclature NACRES : NA.22

Propriétés

• Forme: solid
• Activité optique: [α]20/D +178°, c = 0.5 in chloroform
• Pf: >175 °C
• Température de stockage: 2-8°C
• Chaîne SMILES: CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4
• InChI: 1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1
• Clé InChI: AZFNGPAYDKGCRB-XCPIVNJJSA-M

Description

Description générale

RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Catalyst involved in:

• Asymmetric transfer hydrogenation of imines and ketones
• Intramolecular asymmetric reductive amination
• Tandem hydroformylation / hydrogenation of terminal olefins

Reactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes

Informations légales

Sold in collaboration with Takasago for research purposes only. WO9720789

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Gloves, type N95 (US)