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431567

Sigma-Aldrich

Lithium perchlorate

greener alternative

99.99% trace metals basis

Synonyme(s) :

Perchloric acid, lithium salt

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About This Item

Formule linéaire :
LiClO4
Numéro CAS:
Poids moléculaire :
106.39
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.23

Qualité

ACS reagent

Niveau de qualité

Pureté

99.99% trace metals basis

Forme

granular

Pertinence de la réaction

reagent type: oxidant

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Impuretés

≤0.005% insolubles
<100 ppm total metallic impurities

pH

6.0-7.5

Pf

236 °C (lit.)

Solubilité

H2O: 106.4 g/L at 20 °C

Traces d'anions

chloride (Cl-): ≤0.003%
sulfate (SO42-): ≤0.001%

Autre catégorie plus écologique

Chaîne SMILES 

[Li+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

Clé InChI

MHCFAGZWMAWTNR-UHFFFAOYSA-M

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Description générale

Lithium perchlorate is a white salt that easily dissolves in water. It is commonly employed as an electrolytic salt in batteries due to its excellent electrical impedance, conductivity, hygroscopicity, and anodic stability properties. These characteristics are crucial for its role in battery applications. In addition, it is as a strong oxidizing agent and hence is used as an oxidizer in solid rocket propellants and organic reactions.
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Application

Lithium perchlorate can be used:
  • As a precursor to prepare solid polymer electrolytes for rechargeable Li-ion batteries.
  • As an oxidizer to prepare polymer-based solid propellants.
  • To fabricate cobalt sulfide (CoS)-based counter electrode for dye-sensitized solar cells(DSSC).
Our Lithium perchlorate, with a 99.99% trace metals basis, possesses specific specifications that make it ideal for Lithium-ion batteries. It has low levels of anion traces such as chloride (Cl-): ≤0.003%and sulfate (SO42-): ≤0.001%. Additionally, it contains less than 5 ppm of heavy metals, further enhancing its suitability as an electrolytic salt for Lithium-ion batteries.

Pictogrammes

Flame over circleCorrosionExclamation mark

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

5.1A - Strongly oxidizing hazardous materials

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Lithium garnet based free-standing solid polymer composite membrane for rechargeable lithium battery
K Karthik and Ramaswamy Murugan
Journal of Solid State Electrochemistry, 22, 2989-2998 (2018)
Lithium perchlorate-assisted electrodeposition of CoS catalyst surpassing the performance of platinum in dye sensitized solar cell
Mahir Gulen
Journal of Materials Science, 57, 3513-3524 (2022)
Increased T(c) in electrolyte-gated cuprates.
Anoop Singh Dhoot et al.
Advanced materials (Deerfield Beach, Fla.), 22(23), 2529-2533 (2010-05-07)
S Selvasekarapandian et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 65(5), 1234-1240 (2006-07-11)
The polymer electrolytes composed of poly(vinyl acetate) (PVAc) with various stoichiometric ratios of lithium perchlorate (LiClO(4)) salt have been prepared by solution casting method. The techniques Fourier transform infra-red (FTIR) and Laser Raman spectroscopy have been used to monitor polymer-salt
Shokaku Kim et al.
Organic letters, 4(21), 3735-3737 (2002-10-12)
[reaction: see text] N-Acyliminium cation of prolines was efficiently generated to accumulate in an undivided cell at 0 degrees C by an anodic oxidation of N-acylprolines or alpha'-phenylsulfanylated N-acylproline derivatives in a lithium perchlorate/nitromethane solution. The iminium cation intermediates gave

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