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334049

Sigma-Aldrich

Gold(III) chloride

99%

Synonyme(s) :

Trichlorogold

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About This Item

Formule linéaire :
AuCl3
Numéro CAS:
13453-07-1
Poids moléculaire :
303.33
Numéro CE :
236-623-1
Numéro MDL:
MFCD00014172
Code UNSPSC :
12352302
ID de substance PubChem :
24860214
Nomenclature NACRES :
NA.23

Niveau de qualité

100

Pureté

99%

Forme

powder

Pertinence de la réaction

reagent type: catalyst
core: gold

Chaîne SMILES 

Cl[Au](Cl)Cl

InChI

1S/Au.3ClH/h;3*1H/q+3;;;/p-3

Clé InChI

RJHLTVSLYWWTEF-UHFFFAOYSA-K

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Catégories apparentées

Description générale

Gold(III) chloride is a Lewis acid with monoclinic structure. It is a hygroscopic and light-sensitive solid. It is frequently utilized to dope organic conducting compounds, to boost their conductivity. It also serves as a catalyst in organic synthesis and a precursor to synthesize gold nanoparticles for various electrochemical applications.

Application

Gold(III) chloride can be used:
  • As a dopant to fabricate graphene protection layer between PEDOT:PSS and ITO for perovskite solar cells. It helps to enhance the photoconversion efficiency by protection ITO and collecting holes.
  • To fabricate flexible and transparent electrodes for OLEDs. It fills the defects in graphene and improves current efficiency without affecting the transmittance.
  • As a precursor for green synthesis of gold nanoparticles.

Pictogrammes

Exclamation mark
GHS07

Mention d'avertissement

Warning

Mentions de danger

H315,H319,H335

Classification des risques

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves

Certificats d'analyse (COA)

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A comparative study of galvanic replacement reactions involving Ag nanocubes and AuCl2? or AuCl4?
Au L, et al.
Advanced Materials, 20(13), 2517-2517 (2008)
Ligand-induced gold nanocrystal superlattice formation in colloidal solution.
Lin XM, et al.
Chemistry of Materials, 11(2), 198-202 (1999)
Ahmed A Elzatahry et al.
International journal of nanomedicine, 7, 2829-2832 (2012-06-30)
This report concerns nanofiber composites that incorporate N-heterocyclic carbenes and the use of such composites for testing antimicrobial and antifungal activities. The nanofiber composites were produced by electrospinning mixtures of the gold chloride or gold acetate complexes of a bis(imino)acenaphthene
Vanajakshi Gudla et al.
The Journal of organic chemistry, 76(24), 9919-9933 (2011-10-28)
An intramolecular approach to generate compounds containing an arylnaphthalene lignan scaffold in high yields is presented. It involves a sequential intramolecular electrophilic attack of carbonyl on arylalkyne followed by benzannulation catalyzed by gold salt. AuCl(3) in combination with AgSbF(6) works
Zhi-Xiong Ma et al.
Organic letters, 14(22), 5736-5739 (2012-11-06)
An imino-Nazarov cyclization using α-aryl-substituted allenamides is described. This gold(I)-catalyzed cascade is efficient and regioselective in constructing a diverse array of synthetically useful aromatic-ring fused cyclopentenamides. The success in this transformation represents a solution to the challenge in establishing an
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