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402974

Sigma-Aldrich

Lithium hydroxide monohydrate

ACS reagent, ≥98.0%

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About This Item

Formule linéaire :
LiOH · H2O
Numéro CAS:
Poids moléculaire :
41.96
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NB.24
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Qualité

ACS reagent

Essai

≥98.0%

Forme

powder, crystals or granules

Impuretés

≤0.01% insolubles
≤2.0% Li2CO3

pH

12 (0.4 g/L)

Solubilité

water: soluble 216 g/L at 20 °C

Traces d'anions

chloride (Cl-): ≤0.01%
sulfate (SO42-): ≤0.05%

Traces de cations

Fe: ≤0.002%
heavy metals: ≤20 ppm (by ICP-OES)

Température de stockage

room temp

Chaîne SMILES 

[Li+].O.[OH-]

InChI

1S/Li.2H2O/h;2*1H2/q+1;;/p-1

Clé InChI

GLXDVVHUTZTUQK-UHFFFAOYSA-M

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Description générale

Lithium hydroxide monohydrate is a lithium salt. Crystal structure study reveals it has monoclinic structure with space group C2/m.[1] Its vibrational spectra has been studied using IR, Raman and inelastic neutron scattering (INS) spectroscopy.[2] It is reported to transform the surface of titania monoliths to form flower like structures.[3]

Application

Lithium hydroxide monohydrate may be used to produce naphtoxy ion during the synthesis of allyl 1-naphthyl ethers.[4]
It may be used in the synthesis of the following:
  • Lithium titanate (Li4Ti5O12) heterogeneous nanostructures.[5]
  • Tin oxide-carbon (SnO2/C) nanocomposites.[6]
  • Zinc oxide (ZnO) nanowire arrays.[7]
  • Lithium diborate gel films.[8]
  • Porous layered lithium cobalt oxide (LiCoO2) films.[9]

Pictogrammes

CorrosionExclamation mark

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Code de la classe de stockage

8B - Non-combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Flower-like surface modification of titania materials by lithium hydroxide solution.
Hasegawa G, et al.
Journal of Colloid and Interface Science, 374(1), 291-296 (2012)
Optimization of the ultrasound-assisted synthesis of allyl 1-naphthyl ether using response surface methodology.
dos Santos Fernandes JP, et al.
Ultrasonics Sonochemistry, 18(2), 489-493 (2011)
Synthesis of heterogeneous Li4Ti5O12 nanostructured anodes with long-term cycle stability.
Lee DK, et al.
Nanoscale Research Letters, 5(10), 1585-1589 (2010)
Al-doped ZnO thin film: a new transparent conducting layer for ZnO nanowire-based dye-sensitized solar cells.
Lee SH, et al.
The Journal of Physical Chemistry C, 114(15), 7185-7189 (2010)
Lithium borate gel films prepared from aqueous solution.
Hemry JD, et al.
J. Mater. Sci., 33(15), 3853-3858 (1998)

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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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