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724440

Sigma-Aldrich

9,10-Anthracenedicarboxylic acid

greener alternative

95%

Synonyme(s) :

H2ADC

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About This Item

Formule empirique (notation de Hill):
C16H10O4
Numéro CAS:
73016-08-7
Poids moléculaire :
266.25
Numéro MDL:
MFCD00229428
Code UNSPSC :
26111700
ID de substance PubChem :
329764087
Nomenclature NACRES :
NA.23

Pureté

95%

Forme

solid

Caractéristiques du produit alternatif plus écologique

Design for Energy Efficiency
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sustainability

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Pf

>300 °C

Autre catégorie plus écologique

, Enabling

Chaîne SMILES 

OC(=O)c1c2ccccc2c(C(O)=O)c3ccccc13

InChI

1S/C16H10O4/c17-15(18)13-9-5-1-2-6-10(9)14(16(19)20)12-8-4-3-7-11(12)13/h1-8H,(H,17,18)(H,19,20)

Clé InChI

FDFGHPKPHFUHBP-UHFFFAOYSA-N

Description générale

9,10-Anthracenedicarboxylic acid (H2L) is an anthracene based dicarboxylic compound, which has a larger conjugating π-system that enables the development of fluorescent materials. It has interesting magnetic and luminescent properties. It can be used as a bridging carboxylic acid ligand with a steric bulk due to the presence of its anthracene ring.
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Application

H2L can be potentially used in the formation of highly porous nanotubular and ultramicroporous metal organic frameworks (MOFs) for greener applications like hydrogen storage, methane storage and gas separation.

Pictogrammes

Environment
GHS09

Mention d'avertissement

Warning

Mentions de danger

H400

Conseils de prudence

P273

Classification des risques

Aquatic Acute 1

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Certificats d'analyse (COA)

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Ultramicroporous Metal- Organic Framework Based on 9, 10-Anthracenedicarboxylate for Selective Gas Adsorption
Ma S, et al.
Inorganic Chemistry, 46(21), 8499-8501 (2007)
Manganese (II) complexes with a bulky anthracene-based dicarboxylic ligand: Syntheses, crystal structures, and magnetic properties
Liu C, et al.
Australian Journal of Chemistry, 61(5), 382-390 (2008)
A nanotubular metal-organic framework with permanent porosity: structure analysis and gas sorption studies
Ma S, et al.
Chemical Communications (Cambridge, England), 385(27), 4049-4051 (2009)
Cadmium (II) and lanthanum (III) coordination architectures with anthracene-9, 10-dicarboxylate: Crystal structures and photoluminescent properties
Wang J, et al.
Inorgorganica Chimica Acta, 385(6), 58-64 (2012)
Verena K Gramm et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(12), 2726-2734 (2019-11-28)
Anhydrous EuII -acetylenedicarboxylate (EuADC; ADC2- = - O2 C-C≡C-CO2- ) was synthesized by reaction of EuBr2 with K2 ADC or H2 ADC in degassed water under oxygen-free conditions. EuADC crystallizes in the SrADC type structure (I41 /amd, Z=4) forming a
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