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Sigma-Aldrich

Copper(II) perchlorate hexahydrate

98%

Synonyme(s) :

Cupric perchlorate hexahydrate

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About This Item

Formule linéaire :
Cu(ClO4)2 · 6H2O
Numéro CAS:
10294-46-9
Poids moléculaire :
370.54
Numéro CE :
237-391-4
Numéro MDL:
MFCD00149666
Code UNSPSC :
12352302
ID de substance PubChem :
24852890
Nomenclature NACRES :
NA.23

Pureté

98%

Forme

crystalline

Pertinence de la réaction

reagent type: oxidant

Densité

2.225 g/mL at 25 °C (lit.)

Application(s)

battery manufacturing

Chaîne SMILES 

O.O.O.O.O.O.[Cu++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/2ClHO4.Cu.6H2O/c2*2-1(3,4)5;;;;;;;/h2*(H,2,3,4,5);;6*1H2/q;;+2;;;;;;/p-2

Clé InChI

NHELIHXBJRANPL-UHFFFAOYSA-L

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Description générale

The monoclinic structure of copper perchlorate hexahydrate was analyzed by X-ray diffraction. The product may be used as a catalyst during the reaction of 5-methylisophthalaldehyde with 1,3-diaminopropane. Benzaldehyde semicarbazones, reacted with copper perchlorate hexahydrate in acetonitrile, may yield corresponding 1,2,4-triazolin-5-ones.

Application

  • Methanol[1-(methoxymethanimidoyl)-2-(pyridin-2-ylmethyl)guanidine]bis(perchlorato)copper(II).: This study reports the synthesis and crystal structure of a new copper(II) complex with potential applications in materials science and catalysis. The research focuses on the structural characterization of the complex, which is crucial for understanding its reactivity and potential uses in various chemical processes (Meenongwa et al., 2012).
  • Oxidative cleavage of DNA by a dipyridoquinoxaline copper(II) complex in the presence of ascorbic acid.: This research explores the catalytic activity of a copper(II) complex in oxidative DNA cleavage. The findings demonstrate the complex′s potential application in biochemical studies and the development of new catalytic processes for DNA manipulation and analysis (Santra et al., 2002).

Pictogrammes

Flame over circleExclamation mark
GHS03,GHS07

Mention d'avertissement

Danger

Mentions de danger

H272,H315,H319,H335

Classification des risques

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

5.1A - Strongly oxidizing hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Certificats d'analyse (COA)

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Sze-Wing Ng et al.
Molecules (Basel, Switzerland), 25(9) (2020-05-01)
A new tetradentate mixed aza-thioether macrocyclic ligand 2,6-dithia[7](2,9)-1,10-phenanthrolinophane ([13]ane(phenN2)S2) was successfully synthesized. Reacting metal precursors [Fe(CH3CN)2(OTf)2], Ni(ClO4)2·6H2O, and Cu(ClO4)2·6H2O with one equivalent of [13]ane(phenN2)S2 afforded [Fe([13]ane(phenN2)S2)(OTf)2] (1), [Ni([13]ane(phenN2)S2)](ClO4)2 (2(ClO4)2), and [Cu([13]ane(phenN2)S2)(OH2)](ClO4)2 (3(ClO4)2), respectively. The structures of [13]ane(phenN2)S2 and all of
Sabri Ahmed Cherrak et al.
PloS one, 11(10), e0165575-e0165575 (2016-10-28)
Natural flavonoids such as quercetin, (+)catechin and rutin as well as four methoxylated derivatives of quercetin used as models were investigated to elucidate their impact on the oxidant and antioxidant status of human red blood cells (RBCs). The impact of
The crystal structure of copper perchlorate hexahydrate, Cu (ClO4) 2? 6 H20.
Mani NV and Ramaseshan S
Zeitschrift fur Kristallographie, 115(1-6), 97-109 (1961)
Complexes of binucleating ligands. III. Novel complexes of a macrocyclic binucleating ligand.
Pilkington NH and Robson R
Australian Journal of Chemistry, 23(11), 2225-2236 (1970)
A study of the mechanism of the oxidative cyclization of benzaldehyde semicarbazones induced by cupric perchlorate in acetonitrile
Noto R, et al.
Journal of Heterocyclic Chemistry, 32(4), 1277-1282 (1995)
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