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VOC in an urban and industrial harbor on the French North Sea coast during two contrasted meteorological situations.

Environmental pollution (Barking, Essex : 1987) (2009-07-08)
Joelle Roukos, Véronique Riffault, Nadine Locoge, Hervé Plaisance
RÉSUMÉ

Two measurement campaigns of volatile organic compounds (VOC) were carried out in the industrial city of Dunkerque, using Radiello passive samplers during winter (16-23 January) and summer (6-13 June) 2007. 174 compounds were identified belonging to six chemical families. Classifying sampling sites with similar chemical profiles by hierarchical ascending classification resulted in 4 groups that reflected the influence of the main industrial and urban sources of pollution. Also, the BTEX (Benzene, Toluene, Ethylbenzene and Xylenes) quantification allowed us to map their levels of concentration. Benzene and toluene (BT) showed high concentrations in Northern Dunkerque reflecting the influence of two industrial plants. Differences among spatial distributions of the BT concentrations over contrasted meteorological conditions were also observed. An atypical ratio of T/B in the summer samples led us to investigate the BTEX origins shedding light on the contribution of pollutants transported across various zones of VOC emissions situated in Europe.

MATÉRIAUX
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Marque
Description du produit

Adsorbants cartouches radiello, for sampling BTEX and VOCs (CS2 Desorption), matrix SS net (100 mesh, 5.8 mm diam.), activated with activated charcoal (30-50 mesh), pk of 20
Plaque de support triangulaire Radiello, pk of 20
Corps diffusifs radiello, white, configured for general use, pk of 20
Adsorbants cartouches radiello, for sampling Aldehydes, matrix SS net with 2,4-DNPH coated FLORISIL®, pk of 20
Adsorbants cartouches radiello, for sampling Ammonia (NH3), matrix microporous PE impregnated with phosphoric acid, pk of 20
Corps diffusifs radiello, yellow, configured for reduced sampling rates, pk of 20
Adsorbants cartouches radiello, for sampling BTEX and VOCs (thermal desorption), matrix SS net (3 x 8 μm, 4.8 mm diam.), Carbograph, pk of 20
Corps diffusifs radiello, blue, configured for sampling light sensitive compounds, pk of 20
Abri extérieur radiello, pk of 10
Supelco
radiello Methylene Blue Calibration Standard for H2S (Hydrogen Sulfide), pkg of 100 mL
radiello Barcode Labels, pk of 198
radiello Vertical Adapter, threaded for standard use, pk of 20
radiello BTEX/VOC Starter Kit, CS2 Desorption
Adsorbants cartouches radiello, for sampling Anaesthetic Gases/Vapors, matrix SS net with mix of mol sieve and activated charcoal (30-50 mesh), pk of 20
radiello BTEX/VOC Starter Kit, Thermal Desorption
Supelco
radiello BTEX Calibration Kit (Thermal Desorption)
radiello Filtration Kit, pk of 20
radiello Empty Storage Tubes, polypropylene (with stopper), volume 12 mL, pk of 100
radiello Hydrogen Sulfide Starter Kit
Supelco
radiello BTEX Calibration Kit (CS2 Desorption)
radiello On-Field Thermometer, Includes one standard Radiello vertical adapter (RAD122) for each thermometer, configured for standard use, pk of 3
Supelco
radiello Aldehyde Calibration Standard, 50 μg/mL each component in acetonitrile, pkg of 10 mL
radiello Anesthetic Gases and Vapor Sampler
radiello Empty Storage Tubes, glass (with stopper), volume 2.8 mL, pk of 100
radiello Clips, suspending Radiello triangular support plate, pk of 20
radiello 1,3-Butadiene Starter Kit, Thermal Desorption, pkg of 1 kit (2 RAD141 adsorbing cartridges and barcode labels, 1 RAD1202 yellow diffusive body, 1 RAD121 triangular support plate, 1 instruction sheet)
radiello On-Field Thermometer, Reader, pk of 1
Corps diffusifs radiello, permeative, configured for anaesthetic gases and vapors, pk of 20
radiello Replacement Mounting Strips, for use with Radiello Outdoor Shelter, pk of 100