The specification for this product (95.0 to 98.0 percent) is for the weight percent of the sulfuric acid; the remaining 2 to 5 percent by weight is water. The lot-specific weight percent is reported as the Purity by Sodium Hydroxide (NaOH) titration on the certificate of analysis for each lot. The result is not printed on the bottle. Practically speaking, whether the percentage is 95.0 percent or 98.0 percent or somewhere in between, the material would be handled the same way.
258105
Acide sulfurique
ACS reagent, 95.0-98.0%
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About This Item
Produits recommandés
Qualité
ACS reagent
Niveau de qualité
Agence
suitable for EPA 1613
suitable for SM 4500 - NH3
suitable for SM 5210
Densité de vapeur
<0.3 (25 °C, vs air)
Pression de vapeur
1 mmHg ( 146 °C)
Description
Free from suspended or insoluble matter
Nominally 95-98% H2SO4
Essai
95.0-98.0%
Forme
liquid
Résidus de calcination
≤5 ppm
Couleur
APHA: ≤10
pH
1.2 (5 g/L)
pb
~290 °C (lit.)
Densité
1.840 g/mL at 25 °C (lit.)
Traces d'anions
MnO4- reducers: ≤2 ppm
chloride (Cl-): ≤0.2 ppm
nitrate (NO3-): ≤0.5 ppm
Traces de cations
As: ≤0.01 ppm
Fe: ≤0.2 ppm
Hg: ≤5 ppb
NH4+: ≤2 ppm
heavy metals: ≤1 ppm (by ICP)
Application(s)
PFAS testing
Chaîne SMILES
OS(O)(=O)=O
InChI
1S/H2O4S/c1-5(2,3)4/h(H2,1,2,3,4)
Clé InChI
QAOWNCQODCNURD-UHFFFAOYSA-N
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Catégories apparentées
Application
- dans l'hydrolyse de sels de nitroalcanes primaires et secondaires pour donner des aldéhydes et des cétones.
- dans l'hydrolyse sélective de nitriles et d'amides.
- pour synthétiser des amides de t-alkylcarbinamines via la réaction de Ritter entre des nitriles et des alcènes.
- pour préparer des 3,4-dialkyl-2(5H)-furanones par carbonylation d'aldéhydes α,β-insaturés.
- dans la nitration de carbocycles aromatiques et de composés hétéroaromatiques.
- dans la synthèse de cétones par la réaction de Friedel–Crafts à l'aide d'anhydrides via une réaction d'α-amidoalkylation.
H2SO4 peut aussi être utilisé dans les réactions suivantes :
- Réactions d′addition de Michael
- Réactions de substitution électrophile
- Estérification d'acides aromatiques à fort encombrement stérique
- Réaction d'aldolisation
- Réarrangement de Beckmann
- Réaction de Hofmann–Löffler–Freytag
- Isomérisation
- Déshydrogénation
- Sulfonation
Autres remarques
Mention d'avertissement
Danger
Mentions de danger
Classification des risques
Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A
Code de la classe de stockage
8B - Non-combustible corrosive hazardous materials
Classe de danger pour l'eau (WGK)
WGK 1
Point d'éclair (°F)
Not applicable
Point d'éclair (°C)
Not applicable
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Protocoles
Derived from procedure SSPHYT02. Includes template updates to current SOP specifications and incorporation of notes into the procedure.
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Contenu apparenté
This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.
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Is the range of concentration listed have to do with volume or will an exact percentage be available on the bottle when received for the purposes of further dilution.
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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Difference between 258105-500ML, and 258105-500ML-PC, Mainly the PC part of the partnumber.
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Product 258105-500ML is packaged in a poly bottle, The package sizes listing the -PC suffix, including 258105-500ML-PC, are packaged in PVC-coated glass bottles.
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How was the concentration of Sulfuric acid, Product 258105, calculated?
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The molarity is calculated using the following equation:molarity=[(1000 X Density)/molecular weight] X (percent purity/100).
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What is the concentration of Sulfuric acid, Product 258105, in moles per liter (M)?
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This material has a calculated, theoretical concentration of 18 M.
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How is Sulfuric acid, Product 258105, to be stored?
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This material is a room temperature storage item.
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What is the Department of Transportation shipping information for this product?
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Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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What is Sulfuric acid, Product 258105, dissolved in?
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This material is not dissolved in anything. Rather it is pure sulfuric acid, which is a liquid at room temperature.
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