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C116602

Sigma-Aldrich

Cyclopropanecarboxylic acid

95%

Synonyme(s) :

CPC-acid

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25 G
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100 G
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About This Item

Formule linéaire :
C3H5CO2H
Numéro CAS:
Poids moléculaire :
86.09
Beilstein:
969839
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352100
ID de substance PubChem :
Nomenclature NACRES :
NA.22

70,90 $


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Niveau de qualité

Essai

95%

Forme

liquid

Indice de réfraction

n20/D 1.438 (lit.)

pb

182-184 °C (lit.)

Pf

14-17 °C (lit.)

Densité

1.081 g/mL at 25 °C (lit.)

Température de stockage

2-8°C

Chaîne SMILES 

OC(=O)C1CC1

InChI

1S/C4H6O2/c5-4(6)3-1-2-3/h3H,1-2H2,(H,5,6)

Clé InChI

YMGUBTXCNDTFJI-UHFFFAOYSA-N

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Pictogrammes

Corrosion

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Skin Corr. 1B

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

161.6 °F - closed cup

Point d'éclair (°C)

72 °C - closed cup

Équipement de protection individuelle

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Consulter la Bibliothèque de documents

Perali Ramu Sridhar et al.
Chemical communications (Cambridge, England), 48(5), 756-758 (2011-12-03)
A stereoselective methodology was developed for the construction of C-spiro-glycosides in two steps involving bromonium ion activated solvolytic ring opening of sugar derived 1,2-cyclopropanecarboxylates followed by a one-pot dehydrohalogenation, intramolecular hetero-Michael addition (IHMA) and ester hydrolysis. The obtained spirocyclic lactols
F X Sureda et al.
Neuroreport, 7(11), 1824-1828 (1996-07-29)
The effect of 1-aminocyclopropanecarboxylic acid (ACPC) on the potentiation by glycine of N-methyl-D-aspartate (NMDA)-evoked increases in intracellular free calcium concentration [Ca2+]i was examined in cultured rat cerebellar granule cells. NMDA (50 microM) produced a rapid and sustained increase in [Ca2+]i
Tetsuo Toraya et al.
Applied and environmental microbiology, 70(1), 224-228 (2004-01-09)
A new strain isolated from soil utilizes cyclopropanecarboxylate as the sole source of carbon and energy and was identified as Rhodococcus rhodochrous (H. Nishihara, Y. Ochi, H. Nakano, M. Ando, and T. Toraya, J. Ferment. Bioeng. 80:400-402, 1995). A novel
H M Badawi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 71(4), 1540-1546 (2008-07-05)
The structural stability and internal rotations in cyclopropanecarboxylic acid and cyclopropanecarboxamide were investigated by the DFT-B3LYP and the ab initio MP2 calculations using 6-311G** and 6-311+G** basis sets. The computations were extended to the MP4//MP2/6-311G** and CCSD(T)//MP2/6-311G** single-point calculations. From
Hiroaki Yasukochi et al.
Organic & biomolecular chemistry, 6(3), 540-547 (2008-01-26)
We performed an efficient practical and systematic optical resolution method for gem-dihalo- and monohalocyclopropanecarboxylic acids and utilizing chiral 1,1'-binaphthol monomethyl ether (R)- as the key auxiliary. Direct esterification of with (R)- gave two 1R- and 1S-diastereomeric esters with marked different

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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