794287

Bis[(pinacolato)boryl]methane

• Synonyme(s) : 2,2′-Methylenebis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane], Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methane
• Formule empirique (notation de Hill): C₁₃H₂₆B₂O₄
• Numéro CAS: 78782-17-9
• Poids moléculaire : 267.97
• Numéro MDL: MFCD27977747
• Code UNSPSC : 12352200
• ID de substance PubChem : 329768437
• Nomenclature NACRES : NA.22

Propriétés

• Forme: solid
• Niveau de qualité: 100
• Caractéristiques du produit alternatif plus écologique: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Pf: 48 °C
• Autre catégorie plus écologique: Aligned,
• Température de stockage: 2-8°C
• Chaîne SMILES: CC(C(C)(C)O1)(C)OB1CB2OC(C)(C)C(C)(C)O2
• InChI: 1S/C13H26B2O4/c1-10(2)11(3,4)17-14(16-10)9-15-18-12(5,6)13(7,8)19-15/h9H2,1-8H3
• Clé InChI: MQYZGGWWHUGYDR-UHFFFAOYSA-N

Description

Description générale

Bis[(pinacolato)boryl]methane is an aryl boronate ester.

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Application

Bis-boronate has been reported by Morken and coworkers to be a key building block in the synthesis of enantioenriched secondary boronate esters, which undergo facile Suzuki-Miyaura coupling with minimal erosion of enantiopurity.

Bis[(pinacolato)boryl]methane may be used in the preparation of trans-vinyl boronate esters, via the Boron-Wittig reaction.

Autres remarques

A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates

Informations sur la sécurité

• Pictogrammes: GHS07
• Mention d'avertissement: Warning
• Mentions de danger: H315,H319,H335
• Conseils de prudence: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classification des risques: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3