423734
6-Methyl-1-indanone
99%
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About This Item
Formule empirique (notation de Hill):
C10H10O
Numéro CAS:
Poids moléculaire :
146.19
Numéro MDL:
Code UNSPSC :
12352100
ID de substance PubChem :
Nomenclature NACRES :
NA.22
Produits recommandés
Essai
99%
Forme
solid
pb
70 °C/0.4 mmHg (lit.)
Pf
60-62 °C (lit.)
Groupe fonctionnel
ketone
Chaîne SMILES
Cc1ccc2CCC(=O)c2c1
InChI
1S/C10H10O/c1-7-2-3-8-4-5-10(11)9(8)6-7/h2-3,6H,4-5H2,1H3
Clé InChI
DBOXRDYLMJMQBB-UHFFFAOYSA-N
Description générale
6-Methyl-1-indanone is a substituted indanone. It has been synthesized in high quantum yields by the photolysis of α-chloro-2′,5′-dimethylacetophenone.[1][2] It is formed as one of the photoproduct during the irradiation of 2,5-dimethylphenacyl (DMP) esters.[3] It is reported to be one of the semivolatile component of lamina cigarette smoke.[4]
Application
6-Methyl-1-indanone was used as a starting material for the synthesis of branched alkyl indanes (BINs).[5]
Code de la classe de stockage
11 - Combustible Solids
Classe de danger pour l'eau (WGK)
WGK 3
Point d'éclair (°F)
Not applicable
Point d'éclair (°C)
Not applicable
Équipement de protection individuelle
Eyeshields, Gloves, type N95 (US)
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A laser flash photolysis study of the mechanism of the photocyclization of. alpha.-chloro-ortho-methylacetophenones.
Netto-Ferreira JC and Scaiano JC.
Journal of the American Chemical Society, 113(15), 5800-5803 (1991)
Comparisons of Smoke Components in the Semivolatile Phase from Lamina and Midrib Cigarettes of Flue-cured Tobacco Leaves.
Ishiguro S and Sugawara S.
Agricultural and Biological Chemistry, 42(8), 1527-1531 (1978)
Rapid Photochemical Synthesis of 6-Methyl-1-Indanone.
Wang S, et al.
Advanced Materials Research, 634-638, 416-419 (2013)
2, 5-Dimethylphenacyl as a new photoreleasable protecting group for carboxylic acids.
Klan P, et al.
Organic Letters, 2(11), 1569-1571 (2000)
Andrew M Booth et al.
Environmental science & technology, 42(21), 8122-8126 (2008-11-27)
Previously, comprehensive two-dimensional gas chromatography-time of flight-mass-spectrometry (GCxGC-ToF-MS) revealed that the unresolved complex mixtures (UCMs) of contaminant hydrocarbons accumulated by health-affected mussels Mytilus edulis (up to 125 microg g dry weight(-1)) collected from around U.K. coasts, included many isomeric branched
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