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Sigma-Aldrich

Luperox® DDM-9, 2-Butanone peroxide solution

~35 wt. % in 2,2,4-trimethyl-1,3-pentanediol diisobutyrate

Synonym(s):

2-Butanone peroxide solution, Methyl ethyl ketone peroxide solution

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About This Item

Linear Formula:
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
CAS Number:
1338-23-4
Molecular Weight:
210.22
Beilstein:
1759757
MDL number:
MFCD00042641
UNSPSC Code:
12162002
PubChem Substance ID:
24872944

composition

available oxygen, 8-9%

Quality Level

100

reaction suitability

reagent type: oxidant

concentration

~35 wt. % in 2,2,4-trimethyl-1,3-pentanediol diisobutyrate

refractive index

n20/D 1.437

density

1 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CCC(C)(OO)OOC(C)(CC)OO

InChI

1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3

InChI key

WFUGQJXVXHBTEM-UHFFFAOYSA-N

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Legal Information

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

Signal Word

Danger

Hazard Statements

H242,H314,H361d,H412

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Org. Perox. D - Repr. 2 - Skin Corr. 1B

Storage Class Code

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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T Akaike et al.
Archives of biochemistry and biophysics, 294(1), 55-63 (1992-04-01)
To clarify the nature of cytocidal molecular species among the radicals generated in the iron-catalyzed reactions of peroxides (ROOH), we examined the cytocidal effects of these radicals against gram-positive and gram-negative bacteria in the presence or absence of various radical
M V S Subbalaxmi et al.
The National medical journal of India, 23(3), 150-151 (2010-10-19)
Methyl ethyl ketone peroxide, commonly used in the lamination industry, is a highly inflammable substance. Ingestion of methyl ethyl ketone peroxide is associated with a high morbidity and mortality. It can cause injury to the gastrointestinal tract on ingestion, leading
N Bates et al.
Pediatrics, 108(2), 473-476 (2001-08-03)
A 6-year-old boy developed respiratory distress, metabolic acidosis, severe esophageal and gastric burns, and a coagulopathy after ingestion of an unknown volume of methyl ethyl ketone peroxide (MEKP) in dimethyl phthalate. He was discharged from the pediatric intensive care unit
Allergic contact dermatitis due to methyl ethyl ketone peroxide, cobalt naphthenate and acrylates in the manufacture of fibreglass-reinforced plastics.
Keiko Minamoto et al.
Contact dermatitis, 46(1), 58-59 (2002-03-29)
Yan-Fu Lin et al.
Journal of hazardous materials, 153(3), 1071-1077 (2007-11-09)
Runaway reactions by methyl ethyl ketone peroxide (MEKPO) are an important issue in Asia, due to its unstable structure and extensive heat release during upset situations. This study employed differential scanning calorimetry (DSC) to draw the experimental data for MEKPO
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