CRM01303
Cyantraniliprole
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Sinônimo(s):
3-Bromo-1-(3-chloro-2-pyridyl)-4′-cyano-2′-methyl-6′-(methylcarbamoyl)pyrazole-5-carboxanilide
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About This Item
Fórmula empírica (Notação de Hill):
C19H14BrClN6O2
Número CAS:
Peso molecular:
473.71
Número MDL:
Código UNSPSC:
41116107
NACRES:
NA.24
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grau
certified reference material
TraceCERT®
Nível de qualidade
linha de produto
TraceCERT®
prazo de validade
limited shelf life, expiry date on the label
fabricante/nome comercial
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
temperatura de armazenamento
2-8°C
cadeia de caracteres SMILES
O=C(C1=CC(Br)=NN1C2=C(Cl)C=CC=N2)NC3=C(C(NC)=O)C=C(C#N)C=C3C
InChI
1S/C19H14BrClN6O2/c1-10-6-11(9-22)7-12(18(28)23-2)16(10)25-19(29)14-8-15(20)26-27(14)17-13(21)4-3-5-24-17/h3-8H,1-2H3,(H,23,28)(H,25,29)
chave InChI
DVBUIBGJRQBEDP-UHFFFAOYSA-N
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Descrição geral
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. The CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Cyantraniliprole, a second-generation diamide insecticide, activates the ryanodine receptors of insects to cause the release of Ca2+ ions resulting in muscle paralysis and death of the insect. It shows ovicidal, larvicidal, and adulticide activity, depending upon the pest species. It is used for cereal crops and vegetables, such as rice, peanuts, corn, tomatoes, green onions, and cucumbers for protection against lepidopteran and coleopteran pests.
Cyantraniliprole is approved for use in the European Union. The maximum residue limits (MRL) for cyantraniliprole in food crops, as per EU regulations are in the range of 0.01-15 mg/kg. As per a request received for cyantraniliprole MRL modification by an evaluating member state (EMS) on 28th January 2015, the EFSA has proposed an MRL of 0.5 mg/kg in strawberries, 0.2 mg/kg in the crop groups “herbal infusions from roots” and “root and rhizome spices”, 0.04 mg/kg on beans without pods, 0.15 mg/kg on peas without pods, and 0.1 mg/kg in globe artichokes. No MRL modifications were made for cherries, carrots, root and tuber vegetables, and brussels sprouts. Cyanantraniliprole is monitored in the Multiannual Control Programmes for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Cyantraniliprole, a second-generation diamide insecticide, activates the ryanodine receptors of insects to cause the release of Ca2+ ions resulting in muscle paralysis and death of the insect. It shows ovicidal, larvicidal, and adulticide activity, depending upon the pest species. It is used for cereal crops and vegetables, such as rice, peanuts, corn, tomatoes, green onions, and cucumbers for protection against lepidopteran and coleopteran pests.
Cyantraniliprole is approved for use in the European Union. The maximum residue limits (MRL) for cyantraniliprole in food crops, as per EU regulations are in the range of 0.01-15 mg/kg. As per a request received for cyantraniliprole MRL modification by an evaluating member state (EMS) on 28th January 2015, the EFSA has proposed an MRL of 0.5 mg/kg in strawberries, 0.2 mg/kg in the crop groups “herbal infusions from roots” and “root and rhizome spices”, 0.04 mg/kg on beans without pods, 0.15 mg/kg on peas without pods, and 0.1 mg/kg in globe artichokes. No MRL modifications were made for cherries, carrots, root and tuber vegetables, and brussels sprouts. Cyanantraniliprole is monitored in the Multiannual Control Programmes for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Aplicação
It is intended to be used as a certified reference material (CRM) for calibration in chromatography and other analytical techniques.
Cyantraniliprole certified reference material (CRM) may also find following use:
Cyantraniliprole certified reference material (CRM) may also find following use:
- Study of DNA damage, oxidative stress, and biological toxicity caused in earthworm by cyantraniliprole
- Development of an isotope-labelled internal standard based method using ultra-high-performance liquid chromatography-tandem mass spectrometry for the analysis of chlorantraniliprole and cyantraniliprole in fruits, vegetables, and cereals
- Simultaneous determination of 8 new generation amide insecticides by ultrahigh performance liquid chromatography-tandem mass spectrometry in complex food matrices
- Estimation of five diamide insecticides using carbon nanotube multiplug filter for sample clean-up and ultrahigh-performance liquid chromatography-tandem mass spectrometry in food matrices
- Simultaneous analysis of five diamide insecticides in edible mushrooms by high-performance liquid chromatography coupled to tandem mass spectrometry (HPLC-MS/MS) and a modified QuEChERS procedure for extraction
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Informações legais
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
Palavra indicadora
Warning
Frases de perigo
Declarações de precaução
Classificações de perigo
Aquatic Acute 1 - Aquatic Chronic 1
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
Not applicable
Ponto de fulgor (°C)
Not applicable
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Modification of the existing maximum residue levels for cyantraniliprole in various crops
European Food Safety Authority (EFSA)
EFSA Journal, 4263 null
Zhou Lu et al.
Journal of agricultural and food chemistry, 67(39), 10977-10983 (2019-09-07)
In this study, an analytical method was developed and validated for simultaneous determination of five diamide insecticides (chlorantraniliprole, cyantraniliprole, flubendiamide, cyclaniliprole, and tetrachlorantraniliprole) in food matrices. Determination of the latter two diamide compounds is first reported. Samples were cleaned up
Fajun Tian et al.
Food chemistry, 333, 127468-127468 (2020-07-14)
In this study, a new method for simultaneous determination of cyantraniliprole, chlorantraniliprole, tetrachlorantraniliprole, cyclaniliprole and flubendiamide in edible mushrooms by high-performance liquid chromatography coupled to tandem mass spectrometry (HPLC-MS/MS) combined with a modified QuEChERS procedure. The samples were extracted using
Xinglu Pan et al.
Analytical and bioanalytical chemistry, 407(14), 4111-4120 (2015-03-31)
A reliable and sensitive isotope-labelled internal standard method for simultaneous determination of chlorantraniliprole and cyantraniliprole in fruits (apple and grape), vegetables (cucumber and tomato) and cereals (rice and wheat) using ultra-high-performance liquid chromatography-tandem mass spectrometry was developed. Isotope-labelled internal standards
Tao Lin et al.
Scientific reports, 11(1), 23208-23208 (2021-12-03)
Eight new generation amide insecticide residues analysis by multiwalled carbon nanotubes (MWCNs) cleanup, combined with QuEChERS and ultrahigh performance liquid chromatography tandem mass spectrometry has been developed and successfully applied in complex matrix such as orange, celery, onion, litchi, mango
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