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Sigma-Aldrich

Basolite® C 300

greener alternative

produced by BASF

Sinônimo(s):

Copper benzene-1,3,5-tricarboxylate, Cu-BTC MOF, HKUST-1

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About This Item

Fórmula empírica (Notação de Hill):
C18H6Cu3O12
Peso molecular:
604.87
Número MDL:
MFCD10567003
Código UNSPSC:
26111700
ID de substância PubChem:
329761179
NACRES:
NA.23

grau

produced by BASF

Nível de qualidade

100

Formulário

solid

adequação da reação

reagent type: catalyst
core: copper

características do produto alternativo mais ecológico

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

área da superfície

1500-2100 m2/g

Distribuição do tamanho da partícula

15.96 μm (D50)

densidade volumétrica

0.35 g/cm3

categoria alternativa mais ecológica

, Enabling

cadeia de caracteres SMILES

O=C(O[Cu]OC(=O)c1cc2cc(c1)C(=O)O[Cu]OC2=O)c3cc4cc(c3)C(=O)O[Cu]OC4=O

InChI

1S/2C9H6O6.3Cu/c2*10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15;;;/h2*1-3H,(H,10,11)(H,12,13)(H,14,15);;;/q;;3*+2/p-6

chave InChI

NOSIKKRVQUQXEJ-UHFFFAOYSA-H

Descrição geral

Basolite®C 300 is a metal organic framework (MOF). It is a crystallized hybrid porous solid built up from inorganic subunits, which are connected to organic linkers such as carboxylates or phosphonates. It is a commercialized sorbent that has the structure of HKUST-1.[1][2]
HKUST-1 is also known as MOF-199, Cu-BTC and Basolite(TM) C300. HKUST-1 is a blue cubic crystal of copper based ultramicroporous metal framework (MOF). It is prepared by solvothermal method. It could have a surface area of nearly 2200 m2/g2.[3]
MOF (metal organic framework)
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Aplicação

Basolite®C 300 can be used in the adsorption of carbon dioxide, carbon monoxide, and liquid absorption of dibenzothiopene.[1][4]
Used for gas adsorption (carbon dioxide, nitrogen, oxygen, hydrogen gas), catalysis, and separations

Outras notas

can be reactivated at 200°C (vacuum)

Informações legais

Basolite is a registered trademark of BASF SE

Pictogramas

Skull and crossbonesEnvironment
GHS06,GHS09

Palavra indicadora

Danger

Frases de perigo

H301,H315,H319,H410

Classificações de perigo

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2

Código de classe de armazenamento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificados de análise (COA)

Lot/Batch Number
BCCJ0231
BCCG1834
BCCC1256
BCBZ6293
BCBW8681

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Encontre a documentação dos produtos que você adquiriu recentemente na biblioteca de documentos.

Visite a Biblioteca de Documentos

Jiang, D.; et al.
Catalysis Communications, 12, 602-605 (2011)
Dan Ping Wang et al.
Journal of colloid and interface science, 529, 265-272 (2018-06-17)
A mesoporous octahedral copper oxide@titania (CuO/TiO2) composites with core-shelled structure have been successfully fabricated via a facile and cost-effective approach, which involves two main steps: the creation of homogeneous TiO2 shell onto the octahedral Cu-based metal-organic frameworks (MOFs) template and
Heba Ahmed et al.
Nature communications, 10(1), 2282-2282 (2019-05-28)
The high surface area and porosity, and limitless compound and network combinations between the metal ions and organic ligands making up metal-organic frameworks (MOFs) offer tremendous opportunities for their use in many applications. While numerous methods have been proposed for
Chuanhui Huang et al.
Nature communications, 10(1), 2779-2779 (2019-06-27)
Optimising the supported modes of atom or ion dispersal onto substrates, to synchronously integrate high reactivity and robust stability in catalytic conversion, is an important yet challenging area of research. Here, theoretical calculations first show that three-coordinated copper (Cu) sites
Ayanjeet Ghosh et al.
The journal of physical chemistry letters, 8(21), 5325-5330 (2017-10-13)
We report here the first mesoscale characterization of solvent environments in the metal-organic framework (MOF) Cu
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Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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