407690

tert-Butyl N-(benzyloxy)carbamate

99%

• Fórmula linear: C₆H₅CH₂ONHCO₂C(CH₃)₃
• Número CAS: 79722-21-7
• Peso molecular: 223.27
• Número MDL: MFCD00191873
• Código UNSPSC: 12352100
• ID de substância PubChem: 24865479

Propriedades

• Ensaio: 99%
• pf: 45-47 °C (lit.)
• grupo funcional: amine; phenyl
• cadeia de caracteres SMILES: CC(C)(C)OC(=O)NOCc1ccccc1
• InChI: 1S/C12H17NO3/c1-12(2,3)16-11(14)13-15-9-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3,(H,13,14)
• chave InChI: MZNBNPWFHGWAGH-UHFFFAOYSA-N

Descrição

Descrição geral

tert-Butyl N-(benzyloxy)carbamate (tert-butyl benzyloxycarbamate), a protected hydroxylamine,[1] is an N-alkyl-N-benzyloxy carbamate.[2] Its C-N cross coupling reaction with fluorescein ditriflate has been reported.[1] It participates in facile intramolecular cyclization with various carbon nucleophiles to afford functionalized 5- and 6-membered protected cyclic hydroxamic acids.[2]

Aplicação

tert-Butyl N-(benzyloxy)carbamate was used in the preparation of seven-membered cyclic hydroxamic acids.[2] It may be used in the synthesis of 2-(N-formyl-N-hydroxyamino) ethylphosphonate (IPP).[3]

Informações de segurança

• Pictogramas: GHS07
• Palavra indicadora: Warning
• Frases de perigo: H315,H319,H335
• Declarações de precaução: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classificações de perigo: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Órgãos-alvo: Respiratory system
• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: dust mask type N95 (US), Eyeshields, Gloves