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36295

Sigma-Aldrich

2,3-Dichloro-1-propanol

≥97.0% (GC)

Sinônimo(s):

Glycerol-α,β-dichlorohydrin

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About This Item

Fórmula linear:
ClCH2CHClCH2OH
Número CAS:
616-23-9
Peso molecular:
128.99
Beilstein:
1732060
Número CE:
210-470-0
Número MDL:
MFCD00040446
Código UNSPSC:
12352100
ID de substância PubChem:
57649508
NACRES:
NA.22

Ensaio

≥97.0% (GC)

densidade

1.360 g/mL at 20 °C (lit.)

cadeia de caracteres SMILES

OCC(Cl)CCl

InChI

1S/C3H6Cl2O/c4-1-3(5)2-6/h3,6H,1-2H2

chave InChI

ZXCYIJGIGSDJQQ-UHFFFAOYSA-N

Categorias relacionadas

Descrição geral

2,3-Dichloro-1-propanol belongs to the group of chloropropanols. Inhibitory effects of 2,3-dichloro-1-propanol on T cell both in vivo and in vitro is reported. Improved enantioselective resolution of (R,S)-2,3-dichloro-1-propanol to (S)-2, 3-dichloro-1-propanol by whole cells of a recombinant Escherichia coli in n-heptane-aqueous biphasic system is reported.

Aplicação

2,3-Dichloro-1-propanol may be employed as carbon and energy supplement for the growth of Pseudomonas putida strain (MC4).

Pictogramas

Skull and crossbones
GHS06

Palavra indicadora

Danger

Frases de perigo

H301,H310,H319

Classificações de perigo

Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Eye Irrit. 2

Código de classe de armazenamento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

199.4 °F

Ponto de fulgor (°C)

93 °C

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análise (COA)

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(R)-(−)-3-Chloro-1,2-propanediol 97%, optical purity ee: 98% (GLC)

Sigma-Aldrich

540056

(R)-(−)-3-Chloro-1,2-propanediol

3-Chloro-1-propanol 98%

Sigma-Aldrich

C46403

3-Chloro-1-propanol

Cyclohexanone puriss. p.a., ≥99.5% (GC)

Sigma-Aldrich

29140

Cyclohexanone

(±)-Epichlorohydrin purum, ≥99% (GC)

Sigma-Aldrich

45340

(±)-Epichlorohydrin

(±)-Glycidol analytical standard

Supelco

74595

(±)-Glycidol

Methyl formate anhydrous, 99%

Sigma-Aldrich

291056

Methyl formate

Jing Lu et al.
International immunopharmacology, 17(2), 321-328 (2013-07-16)
2,3-Dichloro-1-propanol (2,3-DCP) is a member of a group of chemicals known as chloropropanols. Currently, immunotoxicity of 2,3-DCP has not been reported. In the present study, we studied its inhibitory effects on T cell both in vivo and in vitro. The
Yoshiki Kuroda et al.
Journal of UOEH, 24(3), 271-280 (2002-09-19)
A rare outbreak of acute hepatic damage in workers exposed to dichloropropanols was reported in 1992. As there are no detailed reports of dichloropropanols (DCPs) toxicity and its mechanism, we reviewed the toxicity of dichloropropanols using our results. 1) A
Shu-Ping Zou et al.
Journal of biotechnology, 188, 42-47 (2014-08-26)
The enantioselective resolution of (R,S)-2,3-dichloro-1-propanol ((R,S)-DCP) to (S)-DCP by whole cells of a recombinant Escherichia coli expressing halohydrin dehalogenase (HHDH) activity was limited by product inhibition. To solve this problem to improve the productivity of (S)-DCP, an n-heptane-aqueous biphasic system
Hassan M Badawi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 75(2), 734-738 (2009-12-22)
The conformational stability and the three rotor internal rotations in 2,3-dichloro-1-propanol were investigated at DFT-B3LYP/6-311+G**, MP2/6-311+G** and MP4(SDQ) levels of theory. From the calculated potential energy surface, ten distinct minima were located all of which were predicted to have real
K Imazu et al.
Journal of UOEH, 14(1), 73-76 (1992-03-01)
We investigated the toxicity of dichloropropanols (DCPs) in hematological findings and serum chemistry. The solutions of two isomers of DCPs, 1,3-dichloro-2-propanol (DC2P) and 2,3-dichloro-1-propanol (DC1P) were dissolved in saline at the concentration of 100 mg/ml, and 0.1 ml of each
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