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Sigma-Aldrich

5-Mercapto-1-methyltetrazole

98%

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About This Item

Fórmula empírica (Notação de Hill):
C2H4N4S
Número CAS:
13183-79-4
Peso molecular:
116.14
Número CE:
236-132-2
Número MDL:
MFCD00037317
Código UNSPSC:
12352100
ID de substância PubChem:
24861949
NACRES:
NA.22

Ensaio

98%

forma

powder

pf

125-128 °C (lit.)

cadeia de caracteres SMILES

Cn1nnnc1S

InChI

1S/C2H4N4S/c1-6-2(7)3-4-5-6/h1H3,(H,3,5,7)

chave InChI

XOHZHMUQBFJTNH-UHFFFAOYSA-N

Descrição geral

5-Mercapto-1-methyltetrazole is a heterocyclic thiol derivative. It forms dimeric or tetrameric complexes with trimethylgallium.

Aplicação

5-Mercapto-1-methyltetrazole may be employed as heterocyclic ligand to study the geometry and stereochemical activity of the lone pair at the lead atom in hemi- and holo-directed lead(II) complexes. It may be used in the chemical modification of submicron particles of mesoporous MSU-2 silica and SBA-15 mesoporous silica.

Pictogramas

Exclamation mark
GHS07

Palavra indicadora

Warning

Frases de perigo

H315,H319,H335

Classificações de perigo

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

4.1A - Other explosive hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Gloves

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T Matsubara et al.
Japanese journal of pharmacology, 45(3), 303-315 (1987-11-01)
The disulfiram-like effect of various beta-lactam antibiotics containing N-methyltetrazolethiol (NMTT) on the alcohol-metabolizing system was studied using rats. Their administration caused decreased activities in low Km aldehyde dehydrogenase (ALDH) and acetaldehyde oxidation in the liver, with marked depression from several
P A Bombardt et al.
Journal of pharmaceutical and biomedical analysis, 8(1), 73-77 (1990-01-01)
A simple, fast and sensitive method for the quantitative determination of 1-methyl-1H-tetrazole-5-thiol using HPLC is reported. Samples are deproteinated by plasma water filtration and injected into a HPLC system capable of column switching and backflushing the analytical column. The limit
Damián Pérez-Quintanilla et al.
Journal of hazardous materials, 166(2-3), 1449-1458 (2009-01-23)
A SBA-15 mesoporous silica has been chemically modified with 5-mercapto-1-methyltetrazole. The newly synthesized material (MTTZ-SBA-15) has been characterized, by powder X-ray diffraction, N(2) adsorption, FT-IR, (13)C NMR spectroscopy and elemental analysis, and used to preconcentrate Zn(II) in water samples. The
L S Welage et al.
Antimicrobial agents and chemotherapy, 33(6), 857-861 (1989-06-01)
The N-methylthiotetrazole side chain (NMTT) that is present on several cephalosporins has been implicated in the development of antibiotic-associated hypoprothrombinemia. A randomized three-way crossover trial was conducted to compare the release of the NMTT side chain from three NMTT-containing antibiotics.
J S Tibbitts et al.
Drug metabolism and drug interactions, 7(2-3), 149-160 (1989-01-01)
The effect of biliary diversion on the ability of cefamandole, a methyltetrazole-thiol (MTT) containing antibiotic, to alter both hepatic vitamin K metabolism and the gamma-carboxylation of glutamic acid were examined in the rat, in order to understand the hypoprothrombinemia associated
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