281409
2-Iodophenol
98%
Sinônimo(s):
1-Iodo-2-hydroxybenzene, 2-Hydroxyiodobenzene, o-Iodophenol
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5 G
R$ 489,00
25 G
R$ 978,00
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5 G
R$ 489,00
25 G
R$ 978,00
About This Item
Fórmula linear:
IC6H4OH
Número CAS:
Peso molecular:
220.01
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22
Produtos recomendados
Nível de qualidade
Ensaio
98%
Formulário
solid
p.e.
186-187 °C/160 mmHg (lit.)
pf
37-40 °C (lit.)
densidade
1.947 g/mL at 25 °C (lit.)
grupo funcional
iodo
cadeia de caracteres SMILES
Oc1ccccc1I
InChI
1S/C6H5IO/c7-5-3-1-2-4-6(5)8/h1-4,8H
chave InChI
KQDJTBPASNJQFQ-UHFFFAOYSA-N
Descrição geral
Rapid palladium-catalyzed carbonylative cyclization reactions of 2-iodophenol with various alkyne under microwave irradiation using Mo(CO)6 as the CO source has been investigated[1].
Palavra indicadora
Warning
Frases de perigo
Declarações de precaução
Classificações de perigo
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Órgãos-alvo
Respiratory system
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
235.4 °F - closed cup
Ponto de fulgor (°C)
113 °C - closed cup
Equipamento de proteção individual
dust mask type N95 (US), Eyeshields, Gloves
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Cao H and Xiao W-J.
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K Suzuki et al.
Journal of biochemistry, 109(5), 791-797 (1991-05-01)
Salicylate hydroxylase [EC 1.14.13.1] from Pseudomonas putida catalyzes the hydroxylation of salicylate, and also o-aminophenol, o-nitrophenol, and o-halogenophenols, to catechol. The reactions with these o-substituted phenols comprise oxygenative deamination, denitration, and dehalogenation, respectively. The reaction stoichiometry, as to NADH oxidized
R Koteshwar Rao et al.
Organic letters, 11(9), 1923-1926 (2009-04-04)
trans-3,4-Dihydro-2H-1,4-benzoxazine moieties can be synthesized by domino aziridine ring opening with o-iodophenols followed by the copper-catalyzed Goldberg coupling cyclization (intramolecular C(aryl)-N(amide) bond formation) with good to excellent yields.
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