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127566

Sigma-Aldrich

Bis(diphenylphosphino)methane

97%

Sinônimo(s):

DPPM, Methanediylbis[diphenylphosphine, Tetraphenylmethylenediphosphine, DPM, Methylenebis(diphenylphosphine)

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About This Item

Fórmula linear:
(C6H5)2PCH2P(C6H5)2
Número CAS:
2071-20-7
Peso molecular:
384.39
Beilstein:
758760
Número CE:
218-194-2
Número MDL:
MFCD00003537
Código UNSPSC:
12352002
ID de substância PubChem:
24847785
NACRES:
NA.22
Preço e disponibilidade não estão disponíveis no momento.

Ensaio

97%

Formulário

solid

adequação da reação

reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

pf

118-119 °C (lit.)

grupo funcional

phosphine

cadeia de caracteres SMILES

C(P(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4

InChI

1S/C25H22P2/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25/h1-20H,21H2

chave InChI

XGCDBGRZEKYHNV-UHFFFAOYSA-N

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Categorias relacionadas

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)

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Certificados de análise (COA)

Lot/Batch Number
MKCT9264
MKCR7848
MKCP3093
MKCM9060
MKCH4256

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Howard Z Ma et al.
Nanoscale, 11(47), 22880-22889 (2019-11-26)
The reactions between silver salts and borohydrides produce a rich set of products that range from discrete mononuclear compounds through to silver nanoparticles and colloids. Previous studies using electrospray ionization mass spectrometry (ESI-MS) to track the cationic products in solutions
Manuela Pardeo et al.
The Journal of rheumatology, 46(9), 1117-1126 (2019-03-03)
To determine whether neutropenia is associated with increased risk for infection in patients with systemic juvenile idiopathic arthritis (sJIA) and polyarticular-course juvenile idiopathic arthritis (pcJIA) treated with tocilizumab (TCZ). Data up to Week 104 from 2 phase III trials of
Walinka van Tol et al.
Journal of inherited metabolic disease, 42(5), 984-992 (2019-04-02)
The congenital disorders of glycosylation (CDG) are inborn errors of metabolism with a great genetic heterogeneity. Most CDG are caused by defects in the N-glycan biosynthesis, leading to multisystem phenotypes. However, the occurrence of tissue-restricted clinical symptoms in the various
Robert R A Freund et al.
Dalton transactions (Cambridge, England : 2003), 43(37), 13988-14000 (2014-08-15)
A series of allyl modified nickelalactone derivatives of the general formula [(L)nNi{CH2C(CH3)C(CH3)CH2COO}] was synthesized via ligand exchange reactions in order to investigate the influence of the neutral ligand L on the structure and stability of these complexes. While the square
Jun-Ichi Wachino et al.
mBio, 11(2) (2020-03-19)
Production of metallo-β-lactamases (MBLs), which hydrolyze carbapenems, is a cause of carbapenem resistance in Enterobacteriaceae Development of effective inhibitors for MBLs is one approach to restore carbapenem efficacy in carbapenem-resistant Enterobacteriaceae (CRE). We report here that sulfamoyl heteroarylcarboxylic acids (SHCs)
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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