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103578

Sigma-Aldrich

4-Nitrodiphenylamine

99%

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About This Item

Fórmula linear:
C6H5NHC6H4NO2
Número CAS:
836-30-6
Peso molecular:
214.22
Número CE:
212-646-2
Número MDL:
MFCD00007301
Código UNSPSC:
12352100
eCl@ss:
39032032
ID de substância PubChem:
24846611
NACRES:
NA.22

Ensaio

99%

forma

solid

pf

132-135 °C (lit.)

cadeia de caracteres SMILES

[O-][N+](=O)c1ccc(Nc2ccccc2)cc1

InChI

1S/C12H10N2O2/c15-14(16)12-8-6-11(7-9-12)13-10-4-2-1-3-5-10/h1-9,13H

chave InChI

XXYMSQQCBUKFHE-UHFFFAOYSA-N

Categorias relacionadas

Descrição geral

4-Nitrodiphenylamine undergoes heterogeneous catalytic transfer hydrogenation to form p-phenylenediamines. 4-Nitrodiphenylamine is used as stabilizer for propellants and explosives.

Aplicação

4-Nitrodiphenylamine was used to study reduction of nitrated diphenylamine derivatives in sediment water batch enrichments and dense cell suspensions of anaerobic, aromatic-compound-mineralizing pure bacterial cultures.

Pictogramas

Exclamation mark
GHS07

Palavra indicadora

Warning

Frases de perigo

H315,H319,H335

Classificações de perigo

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Gloves

Certificados de análise (COA)

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Heterogeneous catalytic transfer hydrogenation of 4-nitrodiphenylamine to p-phenylenediamines.
Banerjee AA and Mukesh D.
Journal of the Chemical Society. Chemical Communications, 18, 1275-1276 (1988)
Anne-Laure Gassner et al.
Science & justice : journal of the Forensic Science Society, 60(2), 136-144 (2020-03-01)
The present study investigated the organic gunshot residue (OGSR) background level of police vehicles in Switzerland. Specimens from 64 vehicles belonging to two regional police services were collected and analysed by LC-MS in positive mode. The driver's and back seats
O Drzyzga et al.
Applied and environmental microbiology, 61(9), 3282-3287 (1995-09-01)
2-Nitrodiphenylamine, 4-nitrodiphenylamine, and 2,4-dinitrodiphenylamine were anaerobically metabolized in sediment-water batch enrichments inoculated with mud from the German North Sea coast. The first intermediate in 2,4-dinitrodiphenylamine degradation was 2-amino-4-nitrodiphenylamine, which appeared in large (nearly stoichiometric) amounts before being completely reduced to
Anne-Laure Gassner et al.
Science & justice : journal of the Forensic Science Society, 59(1), 58-66 (2019-01-19)
The present study aimed at providing data to assess the secondary transfer of organic gunshot residues (OGSR). Three scenarios were evaluated in controlled conditions, namely displacing a firearm from point A to point B, a simple handshake and an arrest
Zuriñe Abrego et al.
The Analyst, 139(23), 6232-6241 (2014-10-11)
A method based on scanning laser ablation and inductively coupled plasma-mass spectrometry (SLA-ICPMS) and Raman micro-spectroscopy for the detection and identification of compounds consistent with gunshot residue particles (GSR) has been developed. The method has been applied to the characterization

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