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933864

Sigma-Aldrich

Dimethyl isosorbide

greener alternative

BioRenewable, anhydrous, DMF and NMP substitute, ≥99%

Synonyme(s) :

Isosorbide dimethyl ether, 1,4:3,6-Dianhydrosorbitol 2,5-dimethyl ether, 1,4:3,6-Dianhydro-2,5-di-O-methyl-D-glucitol, 2,5-Di-O-methyl-1,4:3,6-dianhydro-D-glucitol, DMI

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About This Item

Formule empirique (notation de Hill):
C8H14O4
Numéro CAS:
5306-85-4
Poids moléculaire :
174.19
Numéro Beilstein :
80854
Numéro MDL:
MFCD00064828
Code UNSPSC :
12352005
Nomenclature NACRES :
NA.21

Niveau de qualité

200

Pureté

≥99%

Forme

liquid

Caractéristiques du produit alternatif plus écologique

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Couleur

colorless

Indice de réfraction

n20/D 1.461 (lit.)

Point d'ébullition

93-95 °C/0.1 mmHg (lit.)

Densité

1.15 g/mL at 25 °C (lit.)

Autre catégorie plus écologique

Aligned,

Chaîne SMILES 

CO[C@H]1COC2[C@@H](COC12)OC

InChI

1S/C8H14O4/c1-9-5-3-11-8-6(10-2)4-12-7(5)8/h5-8H,3-4H2,1-2H3/t5-,6+,7-,8-/m1/s1

Clé InChI

MEJYDZQQVZJMPP-ULAWRXDQSA-N

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Description générale

We are dedicated to providing Greener Alternative Products that adhere to The 12 Principles of Greener Chemistry. Dimethyl isosorbide (DMI) is a bio-based solvent that aligns with the principles of "Use of Renewable Feedstocks" and "Safer Solvents and Auxiliaries", making it a sustainable alternative to dipolar aprotic solvents like NMP and DMF. DMI′s high solubilization capacity makes it suitable to be used as a co-solvent for nonpolar drugs and in organic synthesis. Moreover, its exceptional properties, such as non-toxicity, non-irritation, and biodegradability, make it a safe and eco-friendly choice for both customers and the environment.

Application

  • Polymer membranes preparation
  • Peptide synthesis
  • Cross-coupling reactions
  • Co-solvent to improve solubility of nonpolar compounds
  • Lithium battery recycling

Caractéristiques et avantages

  • Bio-based
  • Made from Renewable Resource - straw
  • Non-toxic solvent
  • Non-irritation
  • Biodegradability
  • High solubility potential

Produit(s) apparenté(s)

Réf. du produit
Description
Tarif

414247

2-Methyltetrahydrofuran, BioRenewable, anhydrous, ≥99.0%, contains 250 ppm BHT as stabilizer

673277

2-Methyltetrahydrofuran, BioRenewable, anhydrous, ≥99%, Inhibitor-free

807796

Cyrene™, BioRenewable, DMF and NMP Substitute

906832

Dimethyl isosorbide, BioRenewable, ReagentPlus®, ≥99%

904082

Acétone, BioRenewable, ACS reagent, ≥99.5%

909955

2-Propanol, BioRenewable, ReagentPlus®, ≥99.5%

911046

Glycérol, BioRenewable, ≥99.5%

918660

γ-Valerolactone, BioRenewable, ≥99%, ReagentPlus®

920193

Cyrene™ 2-Methyltetrahydrofuran Blend, BioRenewable, DMF and NMP Substitute

920207

Cyrene™ γ-Valerolactone Blend, BioRenewable, DMF and NMP Substitute

933856

γ-Valerolactone, BioRenewable, anhydrous, DMF and NMP substitute, ≥99%

Code de la classe de stockage

10 - Combustible liquids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

240.8 °F - closed cup

Point d'éclair (°C)

116 °C - closed cup

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Certificats d'analyse (COA)

Lot/Batch Number
SHBR4718
SHBQ9523

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

A sustainable approach to cathode delamination using a green solvent
Onurcan Buken, Kayla Mancinia and Amrita Sarkar
Royal Society of Chemistry Advances, 11, 27356-27368 (2021)
Greening Fmoc/tBu solid-phase peptide synthesis
Musaimi O A, et al.
Green Chemistry, 4, 996-1018 (2020)
Dimethylisosorbide (DMI) as a Bio-Derived Solvent for Pd-Catalyzed Cross-Coupling Reactions
Wilson K L, et al.
Synlett, 29, 2293-2297 (2018)
Dimethyl Isosorbide As a Green Solvent for Sustainable Ultrafiltration and Microfiltration Membrane Preparation
Russo F, et al.
ACS sustainable chemistry & engineering, 8, 659?668-659?668 (2020)
Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Vinyl Acetate in Dimethyl Isosorbide as a Sustainable Solvent
Mincong S, et al.
Organic Letters, 24, 354?358-354?358 (2022)

Contenu apparenté

Biorenewable Solvents

Why should you have to choose between solvents that are ecological and those that are reliable? Enjoy both at once with our biorenewable and greener solutions. Cyrene™ solvent is a new dipolar aprotic alternative to common REACH restricted solvents, such as N methyl-2-pyrrolidone (NMP) and Dimethylformamide (DMF).

Des solvants biorenouvelables

Pourquoi devrait-on choisir entre solvants écologiques et solvants fiables ? Nous vous proposons les deux à la fois grâce à nos solutions biorenouvelables et plus écologiques. Le solvant Cyrene™ est une nouvelle alternative aprotique dipolaire aux solvants courants frappés par la restriction REACH, tels que la N-méthyl-2-pyrrolidone (NMP) et le diméthylformamide (DMF).

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