Accéder au contenu
Merck
Toutes les photos(2)

Principaux documents

Voir toute la documentation

398241

Sigma-Aldrich

Cyclohexanone

ACS reagent, ≥99.0%

Synonyme(s) :

pimelic ketone

Se connecterpour consulter vos tarifs contractuels et ceux de votre entreprise/organisme

Sélectionner une taille de conditionnement

25 ML
43,30 €
500 ML
53,00 €
2 L
136,00 €

43,30 €

Veuillez contacter notre Service Clients pour connaître la disponibilité de ce produit.
Devis pour commande en gros
Toutes les photos(2)

Sélectionner une taille de conditionnement

Changer de vue
25 ML
43,30 €
500 ML
53,00 €
2 L
136,00 €

About This Item

Formule linéaire :
C6H10(=O)
Numéro CAS:
108-94-1
Poids moléculaire :
98.14
Beilstein:
385735
Numéro CE :
203-631-1
Numéro MDL:
MFCD00001625
Code UNSPSC :
12352100
ID de substance PubChem :
24864732
Nomenclature NACRES :
NA.21

43,30 €

Veuillez contacter notre Service Clients pour connaître la disponibilité de ce produit.
Devis pour commande en gros

Qualité

ACS reagent

Niveau de qualité

200

Densité de vapeur

3.4 (vs air)

Pression de vapeur

3.4 mmHg ( 20 °C)

Essai

≥99.0%

Forme

liquid

Température d'inflammation spontanée

788 °F

Limite d'explosivité

1.1 %, 100 °F
9.4 %

dilution

(for analytical testing)

Impuretés

≤0.05% water

Résidus d'évap.

≤0.05%

Couleur

APHA: ≤10

Indice de réfraction

n20/D 1.450 (lit.)

pb

155 °C (lit.)

Pf

−47 °C (lit.)

Densité

0.947 g/mL at 25 °C (lit.)

Groupe fonctionnel

ketone

Chaîne SMILES 

O=C1CCCCC1

InChI

1S/C6H10O/c7-6-4-2-1-3-5-6/h1-5H2

Clé InChI

JHIVVAPYMSGYDF-UHFFFAOYSA-N

Vous recherchez des produits similaires ? Visite Guide de comparaison des produits

Description générale

Cyclohexanone, a colorless liquid is a cyclic ketone. It is an important building block for the synthesis of a variety of organic compounds. Majority of the cyclohexanone synthesized is utilized as an intermediate in the synthesis of nylon.[1] One of the methods reported for its synthesis is by the palladium catalyzed hydrogenation of phenol.[2] The kinetics of the oxidation reaction of cyclohexanone has been studied in a fused silica jet stirred reactor.[3] The Meerwein–Ponndorf–Verley reduction of cyclohexanone has been reported.[4]

Application

  • Application in polymer physicochemical properties: Research highlights the utility of cyclohexanone in developing Poly(vinylidene fluoride) aerogels, emphasizing its role in manipulating polymorphic structures to tune physicochemical characteristics for advanced applications (Suresh et al., 2024).

Pictogrammes

FlameCorrosionExclamation mark
GHS02,GHS05,GHS07

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

111.2 °F - closed cup

Point d'éclair (°C)

44 °C - closed cup

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number
SDBB1478
STBL3447
MKCW6493
MKCW7324
MKCW0104

Vous ne trouvez pas la bonne version ?

Si vous avez besoin d'une version particulière, vous pouvez rechercher un certificat spécifique par le numéro de lot.

Rechercher un(e) COA

Déjà en possession de ce produit ?

Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Les clients ont également consulté

Slide 1 of 5

1 of 5

Hexyl acetate natural, ≥98%, FCC, FG

Sigma-Aldrich

W256528

Hexyl acetate

Cyclopentanone ReagentPlus®, ≥99%

Sigma-Aldrich

C112402

Cyclopentanone

Cyclohexyl-13C6-amine 99 atom % 13C

Sigma-Aldrich

603694

Cyclohexyl-13C6-amine

Cycloheptanone 99%

Sigma-Aldrich

C99000

Cycloheptanone

Cyclohexene analytical standard, ≥99.5% (GC)

Supelco

44028

Cyclohexene

Kinetics of oxidation of cyclohexanone in a jet-stirred reactor: Experimental and modeling.
Serinyel Z, et al.
Proceedings of the Combustion Institute, 35(1), 507-514 (2015)
Supported zirconium-based continuous-flow microreactor for effective Meerwein-Ponndorf-Verley reduction of cyclohexanone.
Koreniuk A, et al.
Catalysis Communications, 64, 48-51 (2015)
Selective transfer hydrogenation of phenol to cyclohexanone on supported palladium catalyst using potassium formate as hydrogen source under open atmosphere.
Patil RD and Sasson Y.
Applied Catalysis A: General, 499, 227-231 (2015)
Synthesis of tetrasubstituted propargylamines from cyclohexanone by solvent-free copper (II) catalysis.
Palchak ZL, et al.
Green Chemistry, 17(3), 1802-1810 (2015)
Green and Sustainable Heterogeneous Organo-Catalyst for Asymmetric Aldol Reactions.
Sadiq M, et al.
Modern Research in Catalysis, 4(2), 43-43 (2015)
Afficher tous les articles scientifiques apparentés

Articles

Baeyer-Villiger Oxidation Reaction

The Baeyer-Villiger oxidation is the oxidative cleavage of a carbon-carbon bond adjacent to a carbonyl, which converts the ketones to esters and the cyclic ketones to lactones.

Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

Reviews

No rating value

Active Filters

Notre équipe de scientifiques dispose d'une expérience dans tous les secteurs de la recherche, notamment en sciences de la vie, science des matériaux, synthèse chimique, chromatographie, analyse et dans de nombreux autres domaines..

Contacter notre Service technique