Accéder au contenu
Merck
Toutes les photos(2)

Principaux documents

B32807

Sigma-Aldrich

Benzyltriphenylphosphonium chloride

99%

Synonyme(s) :

BTPPC, NSC 116712, Triphenyl(phenylmethyl)phosphonium chloride

Se connecterpour consulter vos tarifs contractuels et ceux de votre entreprise/organisme

Sélectionner une taille de conditionnement

25 G
51,90 €
100 G
90,00 €

51,90 €


Veuillez contacter notre Service Clients pour connaître la disponibilité de ce produit.

Devis pour commande en gros

Sélectionner une taille de conditionnement

Changer de vue
25 G
51,90 €
100 G
90,00 €

About This Item

Formule linéaire :
C6H5CH2P(Cl)(C6H5)3
Numéro CAS:
Poids moléculaire :
388.87
Beilstein:
3599868
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352107
ID de substance PubChem :
Nomenclature NACRES :
NA.22

51,90 €


Veuillez contacter notre Service Clients pour connaître la disponibilité de ce produit.

Devis pour commande en gros

Essai

99%

Forme

powder

Capacité de réaction

reaction type: C-C Bond Formation

Pf

≥300 °C (lit.)

Chaîne SMILES 

[Cl-].C(c1ccccc1)[P+](c2ccccc2)(c3ccccc3)c4ccccc4

InChI

1S/C25H22P.ClH/c1-5-13-22(14-6-1)21-26(23-15-7-2-8-16-23,24-17-9-3-10-18-24)25-19-11-4-12-20-25;/h1-20H,21H2;1H/q+1;/p-1

Clé InChI

USFRYJRPHFMVBZ-UHFFFAOYSA-M

Vous recherchez des produits similaires ? Visite Guide de comparaison des produits

Application

Benzyltriphenylphosphonium chloride can be used as a reactant for the synthesis of:
  • Platinum chloro-tetrazole complexes via azidation.[1]
  • Trans-stilbenes and cinnamates via Wittig olefination.[2]
  • Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment.[3]
  • Pentiptycenes for use as light-driven molecular brakes.[4]
  • Archipelago structures for formation of petroleum asphaltenes.[5]


It is also used as a crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites.[6]
Crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites

Reactant for synthesis of:
  • Platinum chloro tetrazole complexes via azidation
  • Trans-stilbenes and cinnamates via Wittig olefination
  • Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment
  • Pentiptycenes for use as light-driven molecular brakes

Reactant for formation of archipelago structures for formation of petroleum asphaltenes

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT RE 1 - STOT SE 3

Organes cibles

Lungs,nasal cavity, Respiratory system

Code de la classe de stockage

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

572.0 °F - closed cup

Point d'éclair (°C)

300 °C - closed cup

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number

Vous ne trouvez pas la bonne version ?

Si vous avez besoin d'une version particulière, vous pouvez rechercher un certificat spécifique par le numéro de lot.

Déjà en possession de ce produit ?

Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Les clients ont également consulté

Synthesis and tyrosinase inhibition activity of trans-stilbene derivatives.
Ismail T, et al.
Bioorganic Chemistry, 64, 97-102 (2016)
Pentiptycene?Derived Light?Driven Molecular Brakes: Substituent Effects of the Brake Component.
Sun W T, et al.
Chemistry?A European Journal , 16(38), 11594-11604 (2010)
Orally active achiral N-hydroxyformamide inhibitors of ADAM-TS4 (aggrecanase-1) and ADAM-TS5 (aggrecanase-2) for the treatment of osteoarthritis.
De Savi , et al.
Bioorganic & Medicinal Chemistry Letters, 21(11), 3301-3306 (2011)
Tube-like natural halloysite/fluoroelastomer nanocomposites with simultaneous enhanced mechanical, dynamic mechanical and thermal properties.
Rooj S, et al.
European Polymer Journal, 47(9), 1746-1755 (2011)
A new route to N (1)-5R-tetrazole complexes via azidation to nitriles coordinated to Pt (II) and Pt (IV).
Popova E A, et al.
Inorgorganica Chimica Acta, 375(1), 242-247 (2011)

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the shelf life for this product?

    1 answer
    1. This product is not assigned an expiration date or recommended retest date. Products with no expiration date or recommended retest date should be routinely inspected by customers to ensure they perform as expected. These products are also subject to a one year warranty from the date of shipment. For more information you may access the "Product Dating Information" document under "ADDITIONAL USEFUL DOCUMENTS ABOUT OUR PRODUCTS" at the bottom of the Quality Services page with this link: https://www.sigmaaldrich.com/life-science/quality-and-regulatory-management/quality-services.

      Helpful?

Reviews

No rating value

Active Filters

Notre équipe de scientifiques dispose d'une expérience dans tous les secteurs de la recherche, notamment en sciences de la vie, science des matériaux, synthèse chimique, chromatographie, analyse et dans de nombreux autres domaines..

Contacter notre Service technique