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Sigma-Aldrich

2-Methyl-2-butene

≥95.0% (GC)

Synonyme(s) :

β-isoamylène, Amylène

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50 ML
47,00 €
250 ML
106,00 €
1 L
293,00 €

About This Item

Formule linéaire :
CH3CH=C(CH3)2
Numéro CAS:
Poids moléculaire :
70.13
Beilstein:
1361353
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352100
ID de substance PubChem :
Nomenclature NACRES :
NA.22

47,00 €


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Densité de vapeur

2.4 (vs air)

Niveau de qualité

Essai

≥95.0% (GC)

Forme

liquid

Limite d'explosivité

8.7 %

Indice de réfraction

n20/D 1.385 (lit.)
n20/D 1.388

pb

35-38 °C (lit.)

Pf

−134 °C (lit.)

Densité

0.662 g/mL at 25 °C (lit.)

Chaîne SMILES 

C\C=C(\C)C

InChI

1S/C5H10/c1-4-5(2)3/h4H,1-3H3

Clé InChI

BKOOMYPCSUNDGP-UHFFFAOYSA-N

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Description générale

2-Methyl-2-butene is a trisubstituted olefin. It acts as guest and forms stable solid host-guest complexes with self-assembled benzophenone bis-urea macrocycles.[1] The impact of active chlorine on photo-oxidation of 2-methyl-2-butene was studied.[2] Photosensitized oxidation of 2-methyl-2-butene adsorbed on internal framework of Na-ZSM-5 zeolite was studied.[3] Gas-phase reaction of 2-methyl-2-butene with ozone has been investigated.[4] Kinetics of liquid-phase alkylation of 3-methylthiophene with 2-methyl-2-butene on supported phosphoric acid has been reported.[5]

[5]2-methyl-2-butene undergoes ultraviolet irradiation, leading to the formation of trimethylene oxides.[6]

Application

2-Methyl-2-butene may be employed as precursor for peroxyacetyl nitrate for the calibration purposes.[4]

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 1 - Muta. 2 - STOT SE 3

Organes cibles

Central nervous system

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

-4.0 °F

Point d'éclair (°C)

-20 °C

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves


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Les clients ont également consulté

Light-catalyzed organic reactions. I. The reaction of carbonyl compounds with 2-methyl-2-butene in the presence of ultraviolet light
Buchi G, et al.
Journal of the American Chemical Society, 76, 4327-4331 (1954)
Kinetics and mechanism of liquid-phase alkylation of 3-methylthiophene with 2-methyl-2-butene over a solid phosphoric acid.
Belliere V, et al.
Applied Catalysis. B, Environmental, 64(3), 254-261 (2006)
Mehdi Nabi et al.
Journal of AOAC International, 103(5), 1243-1249 (2020-11-27)
A simple, rapid, selective and sensitive sample preparation and derivatization method was performed for determination of bromate ions in water by means of dispersive liquid-liquid extraction (DLLE) by gas chromatography-electron capture detection (GC-ECD). This method is based on 2-methyl-2-butene derivatization
Gas-phase reaction of ozone with 2-methyl-2-butene: Dicarbonyl formation from Criegee biradicals.
Grosjean D.
Environmental Science & Technology, 24(9), 1428-1432 (1990)
Light-catalyzed organic reactions. I. The reaction of carbonyl compounds with 2-methyl-2-butene in the presence of ultraviolet light
Buchi G, et al.
Journal of the American Chemical Society, 76, 4327-4331 (1954)

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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