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Sigma-Aldrich

Lithium trifluoromethanesulfonate

greener alternative

99.995% trace metals basis

Synonyme(s) :

LiTf, Lithium triflate, Trifluoromethanesulfonic acid lithium salt

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5 G
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5 G
53,40 €
25 G
147,00 €

About This Item

Formule linéaire :
CF3SO3Li
Numéro CAS:
Poids moléculaire :
156.01
Beilstein:
4301818
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.23

53,40 €


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Niveau de qualité

Essai

99.995% trace metals basis

Forme

powder

Caractéristiques du produit alternatif plus écologique

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Impuretés

≤60 ppm Trace Metal Analysis

Pf

>300 °C (lit.)

Application(s)

battery manufacturing

Autre catégorie plus écologique

Chaîne SMILES 

[Li+].[O-]S(=O)(=O)C(F)(F)F

InChI

1S/CHF3O3S.Li/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1

Clé InChI

MCVFFRWZNYZUIJ-UHFFFAOYSA-M

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Description générale

Lithium trifluoromethanesulfonate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.[1][2][3][4]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

LiOTf can be used for a variety of applications such as:
  • a polymeric layer for light-emitting electrochemical cells[5]
  • an electrolyte for lithium-ion batteries[6]
  • a recyclable catalyst for acetylation of alcohols and diacetylation of aldehydes[7]
  • a separator for supercapacitors[8]

Pictogrammes

Exclamation mark

Mention d'avertissement

Warning

Mentions de danger

Classification des risques

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves


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Certificats d'analyse (COA)

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Lithium trifluoromethanesulfonate (LiOTf) as a recyclable catalyst for highly efficient acetylation of alcohols and diacetylation of aldehydes under mild and neutral reaction conditions
Karimi B and Maleki J
The Journal of Organic Chemistry, 68(12), 4951-4954 (2003)
Development of all-solid-state mediator-enhanced supercapacitors with polyvinylidene fluoride/lithium trifluoromethanesulfonate separators
Zhou J, et al.
Journal of Power Sources, 196(23), 10479-10483 (2011)
Hu, Q.; Osswald, S.; Daniel, R.; Zhu, Y.; Wesel, S.; Ortiz, L.; Sadoway, D.R.
Journal of Power Sources, 196, 5604-5604 (2011)
An improved high-performance lithium-air battery
Jung H, et al.
Nature Chemistry, 4(7), 579-579 (2012)
Polymer light-emitting electrochemical cells: Doping, luminescence, and mobility
Edman L, et al.
Physical Review. B, Condensed Matter and Materials Physics, 70(11), 115212-115212 (2004)

Articles

Solid-state Li batteries: Review of solid electrolytes, ion conduction, structures, and electrochemical processes.

Solid oxide fuel cells and electrolyzers show potential for chemical-to-electrical energy conversion, despite early development stages.

Li-ion batteries are currently the focus of numerous research efforts with applications designed to reduce carbon-based emissions and improve energy storage capabilities.

Lithium-ion batteries offer high energy density and cyclic performance for portable electronic devices.

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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