481130

Gold(I) chloride

99.9% trace metals basis

• Synonyme(s) : Aurous chloride, Gold monochloride
• Formule linéaire : AuCl
• Numéro CAS: 10294-29-8
• Poids moléculaire : 232.42
• Numéro CE : 233-655-8
• Numéro MDL: MFCD00046175
• Code UNSPSC : 12352302
• ID de substance PubChem : 24871740
• Nomenclature NACRES : NA.23
• Essai: 99.9% trace metals basis
• Forme: powder

Propriétés

• Niveau de qualité: 100
• Essai: 99.9% trace metals basis
• Forme: powder
• Pertinence de la réaction: reagent type: catalyst; core: gold
• Impuretés: ≤1500 ppm Trace Metal Analysis
• Pf: 289 °C (dec.) (lit.)
• Densité: 7.57 g/mL at 25 °C (lit.)
• Chaîne SMILES: [Cl-].[Au+]
• InChI: 1S/Au.ClH/h;1H/q+1;/p-1
• Clé InChI: FDWREHZXQUYJFJ-UHFFFAOYSA-M

Description

Description générale

Gold(I) chloride is a yellow crystalline solid with a monoclinic structure. It sublimes at elevated temperatures. Gold(III)chloride is thermally decomposed to produce gold(I) chloride. It is widely used as a precursor to prepare gold nanoparticles and catalyst systems.

Application

Gold(I) chloride can be used:

• As a precursor to prepare magnetic nanocatalyst systems for various organic transformations. For example, Fe₃O₄@SiO₂-P–AuCl can be used as a catalyst for one-pot reductive amination of aldehydes and ketones with various aromatic amines.[1]
• As a starting material to synthesize Au-containing complexes for application in the field of drug delivery, solar cells, sensors, and organic synthesis.[2]
• As a precatalyst for stereoselective cycloisomerization of α-thioallenes to 2,5-dihydrothiophenes via C-S bond formation.[3]
• As a catalyst for the conversion of siloxy cyclohexadienes, to the corresponding1,2- and 1,3-cyclohexenones via Gold-Catalyzed Cycloisomerization.[4]

Informations sur la sécurité

• Pictogrammes: GHS05,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H314,H317
• Conseils de prudence: P260 - P272 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Classification des risques: Skin Corr. 1B - Skin Sens. 1
• Code de la classe de stockage: 8A - Combustible corrosive hazardous materials
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges