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44944

Eisen(III)-chlorid Hexahydrat

puriss. p.a., ACS reagent, crystallized, 98.0-102% (RT)

Synonym(e):

Eisenchlorid

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Größe/SKUVerfügbarkeitPreis
50 g
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€ 29,20
250 g
Warenkorb auf Verfügbarkeit prüfen
€ 69,30
1 kg
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€ 238,00

Über diesen Artikel

Lineare Formel:
FeCl3 · 6H2O
CAS-Nummer:
Molekulargewicht:
270.30
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-729-4
MDL number:
Assay:
98.0-102% (RT)
Form:
crystals or chunks

€ 29,20


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Quality Segment

vapor pressure

1 mmHg ( 194 °C)

grade

ACS reagent, puriss. p.a.

assay

98.0-102% (RT)

form

crystals or chunks

quality

crystallized

impurities

≤0.001% total nitrogen (N), ≤0.002% free chlorine (Cl), ≤0.01% phosphorous compounds (as PO4)

bp

280-285 °C (lit.)

mp

37 °C (lit.)

anion traces

nitrate (NO3-): ≤100 mg/kg, sulfate (SO42-): ≤50 mg/kg

cation traces

As: ≤5 mg/kg, Ca: ≤50 mg/kg, Cd: ≤10 mg/kg, Co: ≤50 mg/kg, Cr: ≤100 mg/kg, Cu: ≤20 mg/kg, Fe2+: ≤20 mg/kg, K: ≤50 mg/kg, Mg: ≤10 mg/kg, Mn: ≤1000 mg/kg, Na: ≤100 mg/kg, Ni: ≤50 mg/kg, Pb: ≤20 mg/kg, Zn: ≤20 mg/kg

SMILES string

O.O.O.O.O.O.Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe.6H2O/h3*1H;;6*1H2/q;;;+3;;;;;;/p-3

InChI key

NQXWGWZJXJUMQB-UHFFFAOYSA-K

General description

Eisen(III)-Chlorid-Hexahydrat kann durch Kristallisierung von Eisen(III)-Chlorid aus Wasser hergestellt werden. Dreidimensionale Einzelkristall-Röntgenbeugungsstudien der Kristallstruktur weisen darauf hin, dass die Kristalle monoklin sind und der Raumgruppe C2h3-2/m angehören.

Application

Eisen(III)-Chlorid-Hexahydrat (FeCl3.6H2O) kann als Oxidationsmittel für die folgenden Umwandlungen verwendet werden:
  • Synthese von of 2-substituierten 4(3H)-Chinazolinonen (Ausbeute = 77–93 %).
  • Oxidation von 1,4-Dihydropyridinen (1,4-DHPs) zu entsprechenden Pyridinen.
  • Oxidation von 4-Isopropyl-1,4-DHP zu dealkyliertem Pyridin.

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Dieser Artikel
940534236489F2877
description

puriss. p.a., ACS reagent, crystallized, 98.0-102% (RT)

description

≥99.99% trace metals basis

description

ACS reagent, 97%

description

reagent grade, ≥98%, chunks

form

crystals or chunks

form

powder or crystals

form

chunks

form

chunks

assay

98.0-102% (RT)

assay

≥99.99% trace metals basis

assay

97%, 97.0-102.0% (ACS specification)

assay

≥98%

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

grade

ACS reagent, puriss. p.a.

grade

-

grade

ACS reagent

grade

reagent grade

impurities

≤0.002% free chlorine (Cl), ≤0.001% total nitrogen (N), ≤0.01% phosphorous compounds (as PO4)

impurities

(≤100ppm trace metals basis)

impurities

≤0.01% P compounds (as PO4), ≤0.1% Substances not pptd. by NH4OH (as sulfates), ≤0.01% insolubles

impurities

-

vapor pressure

1 mmHg ( 194 °C)

vapor pressure

-

vapor pressure

1 mmHg ( 194 °C)

vapor pressure

1 mmHg ( 194 °C)


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pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2

Lagerklasse

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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