8.22340

Phosphorpentachlorid

for synthesis

• Synonym(e): Phosphorpentachlorid
• Empirische Formel (Hill-System): Cl₅P
• CAS-Nummer: 10026-13-8
• Molekulargewicht: 208.24
• MDL-Nummer: MFCD00011439
• UNSPSC-Code: 12352307
• EG-Index-Nummer: 233-060-3
• NACRES: NA.22

Eigenschaften

• Dampfdruck: 0.016 hPa ( 20 °C)
• Qualitätsniveau: 200
• Assay: ≥99.0% (argenometric)
• Form: crystalline solid
• Wirksamkeit: 660 mg/kg LD₅₀, oral (Rat)
• pH-Wert: 1 (5 g/L in H₂O, acidic)
• mp (Schmelzpunkt): 148 °C
• Dichte: 2.1 g/cm³ at 20 °C
• Lagertemp.: 2-30°C
• InChI: 1S/Cl5P/c1-6(2,3,4)5
• InChIKey: UHZYTMXLRWXGPK-UHFFFAOYSA-N

Beschreibung

Anwendung

• Phosphorylation of Glycoluryl Derivatives: New organoelement phosphorus derivatives synthesized using glycoluril and phosphorus pentachloride under controlled conditions (Salkeeva et al., 2021).


• Alcohol Amination and Cyclization: Catalyzed alcohol amination of diethanolamine by a Ru-PNP Pincer complex using phosphorus pentachloride to produce piperazine, demonstrating high conversion rates (van der Loo et al.).


• Chemical Weapons Convention Relevance: Rapid GC-MS screening of chlorides relevant to the Chemical Weapons Convention, including phosphorus pentachloride, for monitoring prohibited chemical activities (Kuitunen et al., 2020).


• Silicon Nanocrystal Functionalization: Phosphorus pentachloride used for the functionalization of silicon nanocrystals, enhancing their utility in advanced materials applications (Islam et al., 2017).

Hinweis zur Analyse

Assay (argentometrisch): ≥ 99,0 %

Sicherheitshinweise

• Piktogramme: GHS05,GHS06,GHS08
• Signalwort: Danger
• H-Sätze: H302 - H314 - H330 - H373
• P-Sätze: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P314
• Gefahreneinstufungen: Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Inhalation
• Zielorgane: Respiratory Tract
• Zusätzliche Gefahrenhinweise: EUH014 - EUH029
• Lagerklassenschlüssel: 6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 1