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8.03068
N,N-Dimethylformamide dimethyl acetal
for synthesis
Synonym(e):
N,N-Dimethylformamide dimethyl acetal, N,N-Dimethyldimethoxymethylamine, DMF-DMA
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Quality Segment
form
liquid
autoignition temp.
155 °C
potency
>5000 mg/kg LD50, oral (Rat)
expl. lim.
1.3-17.7 % (v/v)
pH
7 ( in H2O)
mp
-85 °C
transition temp
flash point 6 °C
density
0.895 g/cm3 at 20 °C
storage temp.
2-30°C
SMILES string
[N+H](C(OC)OC)(C)C
InChI
1S/C5H13NO2/c1-6(2)5(7-3)8-4/h5H,1-4H3/p+1
InChI key
ZSXGLVDWWRXATF-UHFFFAOYSA-O
General description
- As a methylating agent, DMF-DMA has been used in the synthesis of methyl esters from acids, methyl ethers, and thioethers from phenols and aromatic thiols.
- DMF-DMA has been used as a formulating agent to synthesize enamines from active methylenes and active methyl groups, and amidines from amines and amides or thioamide.
- It is also possible to produce heterocyclic compounds using DMF-DMA by cyclizing two functional groups.
Application
- In the synthesis of spirooxindole and pyrazole scaffolds via [3+2] cycloaddition reaction of electron-deficient olefins-based pyrazole motif.
- As a reagent in the synthesis of3-acetyl-4-arylquinoline-based enaminones under microwave irradiation.
Analysis Note
Density (d 20 °C/ 4 °C): 0.893 - 0.897
Identity (IR): passes test
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Signalwort
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Sens. 1
Lagerklasse
3 - Flammable liquids
Was ist los?
WGK 1
Flammpunkt (°F)
42.8 °F
Flammpunkt (°C)
6 °C
Gefahrencodes
Zulassungslistungen
Zulassungslistungen werden hauptsächlich für chemische Produkte erstellt. Für nicht-chemische Produkte können hier nur begrenzte Angaben gemacht werden. Kein Eintrag bedeutet, dass keine der Komponenten gelistet ist. Es liegt in der Verantwortung des Benutzers, die sichere und legale Verwendung des Produkts zu gewährleisten.
68-12-2
68-12-2
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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