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P8533

Tributylammoniumpyrophosphat

powder

Synonym(e):

N,N-dibutyl-1-butanamine diphosphate

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Größe/SKUVerfügbarkeitPreis
250 mg
Warenkorb auf Verfügbarkeit prüfen
€ 66,90
1 g
Warenkorb auf Verfügbarkeit prüfen
€ 188,00
5 g
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€ 570,00

Über diesen Artikel

CAS-Nummer:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22
MDL number:

€ 66,90


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Produktname

Tributylammoniumpyrophosphat,

form

powder

Quality Segment

reaction suitability

core: ammonium, reaction type: phase-transfer, reagent type: organic catalyst

storage temp.

−20°C

SMILES string

OP(O)(=O)OP(O)(O)=O.CCCCN(CCCC)CCCC.CCCCN(CCCC)CCCC

InChI

1S/2C12H27N.H4O7P2/c2*1-4-7-10-13(11-8-5-2)12-9-6-3;1-8(2,3)7-9(4,5)6/h2*4-12H2,1-3H3;(H2,1,2,3)(H2,4,5,6)

InChI key

WRMXOVHLRUVREB-UHFFFAOYSA-N

General description

Tributylammoniumpyrophosphat ist ein Phosphorylierungsreagens, das bei der Synthese von modifizierten dNTP (Desoxynukleosidtriphosphate), die wichtige Basischemikalien für die Erzeugung von DNA, RNA und funktionalisierten Nukleinsäuren darstellen, eingesetzt wird.

Application

Reaktionsmittel für:
  • Enzymische Synthese von 3′-Deoxy-apio-Nukleinsäure-Duplexen
  • Synthese von Desoxynukleosid-S-Methylphosphonsäuren
  • Herstellung von fluoreszierendem nicht nukleotidem ATP-Analogon N-Methylanthraniloylamidethyltriphosphat
Tributylammoniumpyrophosphat wird als Phosphorylierungsreagenz wie folgt eingesetzt:
  • Bei der Synthese von S′-Desoxy-S′-methylphosphonsäure-diphosphat gemeinsam mit 1,1′-Carbonyldiimidazol
  • Bei der Synthese von basenmodifizierten Ribonucleosid-5′-O-triphosphaten auf Gramm-Maßstab
  • Bei der chemischen Ein-Topf-Synthese von 2′-Desoxynucleosid-5′-triphosphaten mit besserem Schutz.

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Dieser Artikel
32243166996290802
description

-

description

97%

description

≥97.0% (T)

description

≥98.0%

reaction suitability

core: ammonium

reaction suitability

core: potassium

reaction suitability

core: ammonium

reaction suitability

core: ammonium

form

powder

form

solid

form

solid

form

crystals

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

storage temp.

−20°C

storage temp.

-

storage temp.

-

storage temp.

-


Lagerklasse

11 - Combustible Solids

Was ist los?

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

PSA (Persönliche Schutzausrüstung)

Eyeshields, Gloves, type N95 (US)



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Analysenzertifikate (COA)

Lot/Batch Number

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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. What is the molecular weight?

    1 answer
    1. The molecular weight is not measured for this tributylammonium pyrophosphate. In literature, the molecular weight is often reported as 548.68 g/mol, assuming a ratio of 2 moles of tributylammonium for every 1 mole of pyrophosphate. The mole ratio of tributylammonium to pyrophosphate is included on the lot-specific certificate of analysis and can be used to calculate the molecular weight.

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

Reviews

Active Filters

  1. USA
    • Review 1
    • Votes 0
    3 out of 5 stars.

    Solubility issues

    Tributylammonium pyrrophosphate is not soluble in water and that is a real pain for me. What does it dissolve in?

    Helpful?

    1. Response from Merck KGaA:

      Thank you for your review. We are sorry to hear that your experience did not match your product expectations. We encourage customers who experience problems with our products to contact us for additional technical support. Please visit https://www.sigmaaldrich.com/US/en/support/customer-support to submit a Product Technical Inquiry.