CF0015

4-Bromophenoxytetrafluorobromoethane

• Lineare Formel: C₈H₄Br₂F₄O
• CAS-Nummer: 113939-45-0
• UNSPSC Code: 12352101
• NACRES: NA.22
• MDL number: MFCD31546217
• Form: liquid

Eigenschaften

• form: liquid
• reaction suitability: reaction type: C-C Bond Formation
• SMILES string: FC(F)(Br)C(F)(F)Oc1ccc(cc1)Br
• InChI: 1S/C8H4Br2F4O/c9-5-1-3-6(4-2-5)15-8(13,14)7(10,11)12/h1-4H
• InChI key: MHPXJSIMKFXETB-UHFFFAOYSA-N

Beschreibung

Application

4-Bromophenoxytetrafluoroethyl bromide is a fluoroalkylbromide that is a radical source of the 4-bromophenoxytetrafluoroethyl moiety. Alternatively, it can also be selectively metallated at the fluorinated carbon with Turbo Grignard reagent at low temperatures resulting in a thermally unstable anion that can act as a nucleophilic fluoroalkylation reagent towards a wide variety of electrophiles, such as aldehydes, ketones or sulfonylimines.The aromatic bromide can be further subjected to Pd-catalyzed cross-coupling reactions to build molecular complexity.

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Other Notes

Technology Spotlight: Fluoroalkylation: Expansion of Togni Reagents

Legal Information

Product of CF Plus Chemicals.

Sicherheitshinweise

• Lagerklasse: 10 - Combustible liquids
• Was ist los?: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable