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Dokumente

B56501

Sigma-Aldrich

4-Bromanisol

≥99.0%

Synonym(e):

1-Brom-4-methoxy-benzol

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About This Item

Lineare Formel:
BrC6H4OCH3
CAS-Nummer:
104-92-7
Molekulargewicht:
187.03
Beilstein:
1237590
EG-Nummer:
203-252-1
MDL-Nummer:
MFCD00000097
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24891850
NACRES:
NA.22

Assay

≥99.0%

Form

liquid

Brechungsindex

n20/D 1.564 (lit.)

bp

223 °C (lit.)

mp (Schmelzpunkt)

9-10 °C (lit.)

Dichte

1.494 g/mL at 25 °C (lit.)

SMILES String

COc1ccc(Br)cc1

InChI

1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3

InChIKey

QJPJQTDYNZXKQF-UHFFFAOYSA-N

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Allgemeine Beschreibung

4-Bromoanisole is a useful brominating reagent. It is formed as reaction product in the reaction between HOBr and anisole. Suzuki coupling of 4-bromoanisole with phenylboronic acid catalyzed by palladium pincer complexes has been studied. Heck Reaction of 4-bromoanisole with ethyl acrylates in room-temperature ionic liquids is reported to afford ethyl 4-methoxycinnamate.

Anwendung

4-Bromoanisole was used in the synthesis of aryl 1,3-diketones.

Piktogramme

Exclamation mark
GHS07

Signalwort

Warning

H-Sätze

H302,H315

Gefahreneinstufungen

Acute Tox. 4 Oral - Skin Irrit. 2

Lagerklassenschlüssel

10 - Combustible liquids

WGK

WGK 2

Flammpunkt (°F)

201.2 °F

Flammpunkt (°C)

94 °C

Persönliche Schutzausrüstung

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Analysenzertifikate (COA)

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Anisol analytical standard

Supelco

96109

Anisol

4′-Bromacetophenon 98%

Sigma-Aldrich

B56404

4′-Bromacetophenon

4-Methoxyphenylborsäure ≥95.0%

Sigma-Aldrich

417599

4-Methoxyphenylborsäure

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