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Dokumente

A29402

Sigma-Aldrich

Allylbenzol

98%

Synonym(e):

3-Phenyl-1-propen

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About This Item

Lineare Formel:
C6H5CH2CH=CH2
CAS-Nummer:
300-57-2
Molekulargewicht:
118.18
Beilstein:
1098501
EG-Nummer:
206-095-7
MDL-Nummer:
MFCD00008651
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24890709
NACRES:
NA.22

Assay

98%

Form

liquid

Brechungsindex

n20/D 1.511 (lit.)

bp

156-157 °C (lit.)

Dichte

0.892 g/mL at 25 °C (lit.)

SMILES String

C=CCc1ccccc1

InChI

1S/C9H10/c1-2-6-9-7-4-3-5-8-9/h2-5,7-8H,1,6H2

InChIKey

HJWLCRVIBGQPNF-UHFFFAOYSA-N

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Allgemeine Beschreibung

Allylbenzene, also known as 3-phenylpropene, is an organic compound used as a source of the allyl group in allylation reactions.

Piktogramme

FlameHealth hazard
GHS02,GHS08

Signalwort

Danger

H-Sätze

H226,H304

Gefahreneinstufungen

Asp. Tox. 1 - Flam. Liq. 3

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 3

Flammpunkt (°F)

104.0 °F - closed cup

Flammpunkt (°C)

40 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Analysenzertifikate (COA)

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1 of 1

3-Phenyl-1-propin contains ca.250 ppm BHT as inhibitor, 97%

Sigma-Aldrich

376841

3-Phenyl-1-propin

Eric A Standley et al.
Journal of the American Chemical Society, 135(4), 1585-1592 (2013-01-16)
The synthesis and characterization of the air-stable nickel(II) complex trans-(PCy(2)Ph)(2)Ni(o-tolyl)Cl is described in conjunction with an investigation of its use for the Mizoroki-Heck-type, room temperature, internally selective coupling of substituted benzyl chlorides with terminal alkenes. This reaction, which employs a
Mitsuo Miyazawa et al.
Natural product research, 19(1), 29-36 (2005-02-11)
A methanol extract from Asiasarum heterotropoides showed a suppressive effect of the SOS-including activity on the mutagen 2-amino-3,4-dimethylimidazo[4,5-f]quinoline (MeIQ) in the Salmonella typhimurium TA1535/pSK1002 umu test. The methanol extract was re-extracted with chloroform, butanol, and water. The chloroform fraction showed
J R Idle
Prague medical report, 106(1), 27-38 (2005-07-13)
The typical spices used in winter include nutmeg, cinnamon, clove and anise. These spices contain two groups of chemicals, the allylbenzenes and their isomers, the propenylbenzenes. It was suggested 40 years ago by Alexander Shulgin that these substances act as
Thi X Thi Luu et al.
Molecules (Basel, Switzerland), 14(9), 3411-3424 (2009-09-29)
Essential oil allylbenzenes from have been converted quickly and efficiently into the corresponding benzaldehydes in good yields by a two-step "green" reaction pathway based on a solventless alkene group isomerization by KF/Al(2)O(3) to form the corresponding 1-arylpropene and a subsequent
P G Debrunner et al.
Proceedings of the National Academy of Sciences of the United States of America, 93(23), 12791-12798 (1996-11-12)
We have used Mössbauer and electron paramagnetic resonance (EPR) spectroscopy to study a heme-N-alkylated derivative of chloroperoxidase (CPO) prepared by mechanism-based inactivation with allylbenzene and hydrogen peroxide. The freshly prepared inactivated enzyme ("green CPO") displayed a nearly pure low-spin ferric
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