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90795

Tributylborat

≥99.0% (T)

Synonym(e):

Borsäure-tributylester, Tributoxyboran

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Größe/SKUVerfügbarkeitPreis
100 mL
Warenkorb auf Verfügbarkeit prüfen
€ 106,00
500 mL
Warenkorb auf Verfügbarkeit prüfen
€ 163,00

Über diesen Artikel

Lineare Formel:
[CH3(CH2)3O]3B
CAS-Nummer:
Molekulargewicht:
230.15
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-706-5
Beilstein/REAXYS Number:
1703865
MDL number:
Assay:
≥99.0% (T)
Form:
liquid

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vapor density

7.95 (vs air)

Quality Segment

assay

≥99.0% (T)

form

liquid

refractive index

n20/D 1.409

bp

114-115 °C/12 mmHg (lit.), 230-235 °C (lit.)

mp

−70 °C (lit.)

density

0.853 g/mL at 25 °C (lit.)

SMILES string

CCCCOB(OCCCC)OCCCC

InChI

1S/C12H27BO3/c1-4-7-10-14-13(15-11-8-5-2)16-12-9-6-3/h4-12H2,1-3H3

InChI key

LGQXXHMEBUOXRP-UHFFFAOYSA-N

General description

Tributyl borate is an organoboron compound, that is often used as a reagent in organic synthesis for the preparation of various boronic acid derivatives, which are widely used in Suzuki coupling reactions in the synthesis of biaryls and other organic molecules. It is also used as a catalyst in a range of organic reactions, including the transesterification of esters and Biginelli reactions.

Application

Tributyl borate can be used as:    
  • A catalyst in the synthesis of dihydropyrimidinone derivatives via the Biginelli reaction.   
  • A boron oxide source to prepare carbon nanotube-B2O3 nanocomposite by solvothermal method.


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Dieser Artikel
0067590827247049
description

≥99.0% (T)

description

for extraction analysis, ≥99.0% (GC)

description

≥93.5% (Tri-N-butylphosphine, GC)

description

mixture of isomers, 97%

assay

≥99.0% (T)

assay

≥99.0% (GC)

assay

≥97% (Tri-N-butylphospine + isomers), ≥93.5% (Tri-N-butylphosphine, GC)

assay

97%

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

200

mp

−70 °C (lit.)

mp

−79 °C (lit.)

mp

-

mp

-

form

liquid

form

liquid

form

liquid

form

liquid

density

0.853 g/mL at 25 °C (lit.)

density

0.979 g/mL at 25 °C (lit.)

density

0.81 g/mL at 25 °C (lit.)

density

0.81 g/mL at 25 °C (lit.)

refractive index

n20/D 1.409

refractive index

n20/D 1.424

refractive index

n20/D 1.462 (lit.), n20/D 1.463

refractive index

n20/D 1.462 (lit.)


Piktogramme

Exclamation mark

Signalwort

Warning

Gefahrencodes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklasse

10 - Combustible liquids

Was ist los?

WGK 3

Flammpunkt (°F)

158.0 °F - closed cup

Flammpunkt (°C)

70 °C - closed cup

PSA (Persönliche Schutzausrüstung)

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Analysenzertifikate (COA)

Lot/Batch Number

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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