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9,9′-Spirobifluorene
97%
Synonym(e):
9,9′-Spirobi[9H-fluorene]
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About This Item
Empirische Formel (Hill-System):
C25H16
CAS-Nummer:
Molekulargewicht:
316.39
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.23
Empfohlene Produkte
Assay
97%
Form
solid
mp (Schmelzpunkt)
195-200 °C
SMILES String
c1ccc2c(c1)-c3ccccc3C24c5ccccc5-c6ccccc46
InChI
1S/C25H16/c1-5-13-21-17(9-1)18-10-2-6-14-22(18)25(21)23-15-7-3-11-19(23)20-12-4-8-16-24(20)25/h1-16H
InChIKey
SNFCXVRWFNAHQX-UHFFFAOYSA-N
Allgemeine Beschreibung
9,9′-Spirobifluorene is a polyfluorene with carbon atoms of the methylene bridge connected to two fluorene molecules. It is mainly used in organic electronics due to its robust structure and two perpendicularly arranged π systems.
Anwendung
9,9′-Spirobifluorene can be used in the synthesis of spirobifluorene based conjugated microporous polymers which can be potentially be used as a gas absorbent. It may be used as a hole transporting material which can be used in the fabrication of perovskite solar cells.
Leistungsmerkmale und Vorteile
High glass-transition temperature, excellent thermal stability, soluble in common organic solvents, multi-layer devices can be fabricated by thermal cross-linking of cast films. Easy colour tunability through the introduction of low band gap co-monomers.
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
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Photocatalytic H2 Evolution by Pt-Loaded 9, 9?-Spirobifluorene-Based Conjugated Microporous Polymers under Visible-Light Irradiation.
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Organic Light Emitting Diode (OLED) materials from spirobifluorene derivatives
R. N. Jana, S. Chakraborty, R. Banerjee
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Anodic oxidation of 9, 9?-spirobifluorene in CH2Cl2+ 0.2 M Bu4NBF4. Electrochemical behaviour of the derived oxidation product.
Rault-Berthelot J, et al.
Synthetic Metals, 97(3), 211-215 (1998)
Synthesis of 9, 9?-spirobifluorene-based conjugated microporous polymers by FeCl 3-mediated polymerization.
Modak A, et al.
Polym. Chem., 7(6), 1290-1296 (2016)
Amorphous poly-2, 7-fluorene networks
Marsitzky, D., Murray, J., Scott, J. C., & Carter, K. R.
Chemistry of Materials, 13(11), 4285-4289 (2001)
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