761206

4-Pentenylmagnesium bromide solution

0.5 M in THF

• Synonym(e): 4-Pentene-1-magnesium bromide solution
• Empirische Formel (Hill-System): C₅H₉BrMg
• Molekulargewicht: 173.33
• MDL-Nummer: MFCD11553331
• UNSPSC-Code: 12352302
• PubChem Substanz-ID: 329766914
• NACRES: NA.22

Eigenschaften

• Form: solution
• Eignung der Reaktion: reaction type: Grignard Reaction
• Konzentration: 0.5 M in THF
• Dichte: 0.940 g/mL at 25 °C
• SMILES String: Br[Mg]CCCC=C
• InChI: 1S/C5H9.BrH.Mg/c1-3-5-4-2;;/h3H,1-2,4-5H2;1H;/q;;+1/p-1
• InChIKey: LHTUYNSQNJOCCB-UHFFFAOYSA-M

Beschreibung

Anwendung

4-Pentenylmagnesium bromide is a general Grignard reagent used in the total synthesis of (−)-sarain A, (−)-salicylihalamide A and (+)-erysotramidine. It is also used in the synthesis of hexa-peri-hexabenzocoronene cyclophane.

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H260,H302,H314,H335,H351
• P-Sätze: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• Gefahreneinstufungen: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• Zielorgane: Respiratory system
• Zusätzliche Gefahrenhinweise: EUH019
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flammpunkt (°F): 11.8 °F - closed cup
• Flammpunkt (°C): -11.2 °C - closed cup