710563

Tris(o-methoxyphenyl)phosphin

96%, powder

• Synonym(e): NSC 93545, Tris(o-anisyl)phosphine
• Empirische Formel (Hill-System): C₂₁H₂₁O₃P
• CAS-Nummer: 4731-65-1
• Molekulargewicht: 352.36
• NACRES: NA.22
• PubChem Substance ID: 329762934
• UNSPSC Code: 12352112
• EC Number: 225-235-8
• MDL number: MFCD00014892

Eigenschaften

• Produktname: Tris(o-methoxyphenyl)phosphin, 96%
• assay: 96%
• form: powder
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
• mp: 198-204 °C
• functional group: phosphine
• SMILES string: COc1ccccc1P(c2ccccc2OC)c3ccccc3OC
• InChI: 1S/C21H21O3P/c1-22-16-10-4-7-13-19(16)25(20-14-8-5-11-17(20)23-2)21-15-9-6-12-18(21)24-3/h4-15H,1-3H3
• InChI key: IIOSDXGZLBPOHD-UHFFFAOYSA-N

Beschreibung

Application

Catalyst for:

• Allylic substitution of simple alkenes
• Suzuki coupling reactions
• Telomerization of 1,3-butadiene with various alcohols
• Hydrogenation of quinolines
• Amination / direct arylation

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• Gefahrencodes: H315,H319,H335,H413
• Sicherheitshinweise: P273 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklasse: 11 - Combustible Solids
• Was ist los?: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• PSA (Persönliche Schutzausrüstung): dust mask type N95 (US), Eyeshields, Gloves