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Merck

703206

Sigma-Aldrich

cis-Bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II)

Synonym(e):

N-3-Farbstoff

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About This Item

Empirische Formel (Hill-System):
C26H16N6O8RuS2
CAS-Nummer:
Molekulargewicht:
705.64
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.23

Assay

95% (NMR)

Form

powder

mp (Schmelzpunkt)

>300 °C

λmax

534, 395, 312 nm (lit.)

SMILES String

S=C=N[Ru]N=C=S.OC(=O)c1ccnc(c1)-c2cc(ccn2)C(O)=O.OC(=O)c3ccnc(c3)-c4cc(ccn4)C(O)=O

InChI

1S/2C12H8N2O4.2CNS.Ru/c2*15-11(16)7-1-3-13-9(5-7)10-6-8(12(17)18)2-4-14-10;2*2-1-3;/h2*1-6H,(H,15,16)(H,17,18);;;/q;;2*-1;+2

InChIKey

VMISXESAJBVFNH-UHFFFAOYSA-N

Allgemeine Beschreibung

cis-Bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II) (N3 dye) is a ruthenium polypyridyl based complex that can be used as a sensitizer. It is a highly stable polymer in which the photocurrent decreases with an increase in the concentration of N3 dye.

Anwendung

N3 dye can be coated on electrodes for improving the sensitivity of the dye sensitized solar cells (DSSCs) which can further enhance the power conversion efficiency (PCE).

Rechtliche Hinweise

Product of Dyesol® exclusive supplier of Sun2 products under license from EPFL.
Dyesol is a registered trademark of Greatcell Solar

Piktogramme

Exclamation mark

Signalwort

Warning

Gefahreneinstufungen

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


Analysenzertifikate (COA)

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Stark effects after excited-state interfacial electron transfer at sensitized TiO2 nanocrystallites
Ardo S, et al.
Journal of the American Chemical Society, 132(19), 6696-6709 (2010)
Ruthenium (II) Charge-Transfer Sensitizers Containing 4, 4 `-Dicarboxy-2, 2 `-bipyridine. Synthesis, Properties, and Bonding Mode of Coordinated Thio-and Selenocyanates
Kohle O, et al.
Inorganic Chemistry, 35(16), 4779-4787 (1996)
Determination of the electron lifetime in nanocrystalline dye solar cells by open-circuit voltage decay measurements
Zaban A, et al.
ChemPhysChem, 4(8), 859-864 (2003)
Influence of electrolyte in transport and recombination in dye-sensitized solar cells studied by impedance spectroscopy
Fabregat-Santiago F, et al.
Solar Energy Materials and Solar Cells, 87(1-4), 117-131 (2005)
Transport-limited recombination of photocarriers in dye-sensitized nanocrystalline TiO2 solar cells
Kopidakis N, et al.
The Journal of Physical Chemistry B, 107(41), 11307-11315 (2003)

Artikel

Dye-sensitized solar cells directly convert sunlight to electricity

Dye-sensitized solar cells (DSSCs) attract attention for high performance and potential low-cost production in solar energy.

Operation principle and market dominance of single crystalline silicon solar cells.

Organic materials in optoelectronic devices like LEDs and solar cells are of significant academic and commercial interest.

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