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700665
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxid
Synonym(e):
(R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate
Größe auswählen
| Größe/SKU | Verfügbarkeit | Preis |
|---|---|---|
100 mg | Warenkorb auf Verfügbarkeit prüfen | € 283,00 |
Über diesen Artikel
form
solid
Quality Segment
optical activity
[α]22/D −44.0°, c = 1 in DMSO
reaction suitability
reagent type: organic catalyst
mp
390-400 °C
functional group
phosphate
storage temp.
−20°C
SMILES string
OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)-c6cc7ccccc7c8ccccc68)-c9cc%10ccccc%10c%11ccccc9%11
InChI
1S/C48H29O4P/c49-53(50)51-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)52-53)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28H,(H,49,50)
InChI key
BVICVEIKBNVROI-UHFFFAOYSA-N
Application
- Asymmetric hydrogenation cascade
- Enantioselective Friedel-Crafts reaction
- Asymmetric hydrogenation of 2-substituted quinolines
- Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
- Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
- Asymmetric transfer hydrogenation of substituted quinoxalines
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Dieser Artikel | |||
|---|---|---|---|
| description - | description - | description - | description - |
| reaction suitability reagent type: organic catalyst | reaction suitability - | reaction suitability - | reaction suitability - |
| functional group phosphate | functional group amine, phosphine | functional group amine | functional group - |
| form solid | form solid | form solid | form solid |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| storage temp. −20°C | storage temp. 2-8°C | storage temp. - | storage temp. - |
| optical activity [α]22/D −44.0°, c = 1 in DMSO | optical activity - | optical activity [α]22/D 282.0°, c = 1 in chloroform | optical activity [α]22/D +270°, c = 1 in chloroform |
![(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxid](/deepweb/assets/sigmaaldrich/product/structures/340/448/84d0af38-2286-4204-b2fa-7ce44f4b40bc/640/84d0af38-2286-4204-b2fa-7ce44f4b40bc.png)
![(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1′,2′-f]-1,3,2-Dioxaphosphepin-4-Amin](/deepweb/assets/sigmaaldrich/product/structures/260/755/3101c3e8-e884-4803-ba52-a87c7e168847/640/3101c3e8-e884-4803-ba52-a87c7e168847.png)
![(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-Amin](/deepweb/assets/sigmaaldrich/product/structures/367/001/fbed2f38-c473-44d8-b6de-d4a577ea3923/640/fbed2f38-c473-44d8-b6de-d4a577ea3923.png)
![(11bR,11′bR)-4,4′-(9,9-Dimethyl-9H-xanthen-4,5-diyl)bis-dinaphtho[2,1-d:1′, 2′-f][1,3,2]dioxaphosphepin](/deepweb/assets/sigmaaldrich/product/structures/198/331/bd88130d-f49e-4bc8-b82e-5e43b3bcea95/640/bd88130d-f49e-4bc8-b82e-5e43b3bcea95.png)
Lagerklasse
11 - Combustible Solids
Was ist los?
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
PSA (Persönliche Schutzausrüstung)
Eyeshields, Gloves, type N95 (US)
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