692808

(R,R)-DACH-phenyl Trost-Ligand

95%

• Synonym(e): (1R,2R)-(+)-1,2-Diaminocyclohexan-N,N′-bis-(2-diphenylphosphinobenzoyl)
• Empirische Formel (Hill-System): C₄₄H₄₀N₂O₂P₂
• CAS-Nummer: 138517-61-0
• Molekulargewicht: 690.75
• NACRES: NA.22
• PubChem Substance ID: 329761529
• UNSPSC Code: 12352002
• MDL number: MFCD01631273

Eigenschaften

• Quality Segment: 100
• assay: 95%
• form: solid
• optical activity: [α]20/D +131°, c = 1 in methanol
• reaction suitability: reagent type: chrial catalyst
• manufacturer/tradename: ECACC
• mp: 136-142 °C
• functional group: amide, phosphine
• SMILES string: O=C(N[C@@H]1CCCC[C@H]1NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7
• InChI: 1S/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m1/s1
• InChI key: AXMSEDAJMGFTLR-XRSDMRJBSA-N

Beschreibung

Application

Asymmetirc allylic alkylation ligand.

Trost Ligands for Asymmetric Allylic Alkylation

Legal Information

Sold in collaboration with Dr. Reddy′s Laboratories for research purposes only. US Patent 5739396 applies.

Sicherheitshinweise

• Lagerklasse: 11 - Combustible Solids
• Was ist los?: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable