682322

(R)-N-Methyl-N-diphenylphosphino-1-[(S)-2-diphenylphosphino)ferrocenyl]ethylamin

≥96%

• Synonym(e): (1R)-1-(Diphenylphosphino)-2-[(1R)-1-[(diphenylphosphino)-methylamino]-ethyl]-ferrocen, Methyl-BoPhoz
• Empirische Formel (Hill-System): C₃₇H₃₅FeNP₂
• CAS-Nummer: 406680-94-2
• Molekulargewicht: 611.47
• MDL-Nummer: MFCD05865220
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329760488
• NACRES: NA.22

Eigenschaften

• Assay: ≥96%
• Form: solid
• mp (Schmelzpunkt): 108.7-113.6 °C
• SMILES String: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)P(c5ccccc5)c6ccccc6
• InChI: 1S/C32H30NP2.C5H5.Fe/c1-26(33(2)35(29-20-11-5-12-21-29)30-22-13-6-14-23-30)31-24-15-25-32(31)34(27-16-7-3-8-17-27)28-18-9-4-10-19-28;1-2-4-5-3-1;/h3-26H,1-2H3;1-5H;/t26-;;/m1../s1
• InChIKey: ZIAZHUWEJYUGEO-FBHGDYMESA-N

Beschreibung

Anwendung

Efficient ligand for asymmetric hydrogenation

(R)-N-Methyl-N-diphenylphosphino-1-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine-rhodium complex can efficiently catalyze the asymmetric hydrogenation of 2-tert-butoxycarbonylamino-3-cyclopropylacrylic acid benzyl ester to form (S)-2-tert-butoxycarbonylamino-3-cyclopropylpropionic acid benzyl ester.

Rechtliche Hinweise

Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US6590115 and any patents arising therefrom apply.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable